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引用本文:施锦杰,邓晨皓,张亚梅.钢筋在碱激发矿渣砂浆中的早期腐蚀行为[J].建筑材料学报,2016,19(6):969-975
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钢筋在碱激发矿渣砂浆中的早期腐蚀行为
施锦杰, 邓晨皓, 张亚梅
东南大学材料科学与工程学院,江苏南京211189
摘要:
研究了模拟海水干湿循环过程中海水拌和碱激发矿渣(SAAS)砂浆、自来水拌和碱激发矿渣(TAAS)砂浆及矿渣水泥复合(CS)砂浆的强度变化.同时,通过腐蚀电位、线性极化电阻、电化学阻抗谱法研究了低碳钢筋(LC)和低合金耐蚀钢筋(LA)在上述3种砂浆中的早期腐蚀行为.结果表明:模拟海水干湿循环过程中,SAAS砂浆表现出较CS砂浆更高的强度保证;SAAS砂浆中钢筋早期腐蚀行为与TAAS砂浆无明显区别;钢筋在SAAS砂浆及CS砂浆中的极化电阻及电荷转移电阻在6个月的干湿循环过程中整体呈上升趋势,表现出较低的腐蚀程度.
关键词:  模拟海水  碱激发矿渣  钢筋  电化学方法
DOI:10.3969/j.issn.1007 9629.2016.06.003
分类号:
基金项目:国家重点基础研究发展计划(973计划)项目(2015CB655100);国家自然科学基金资助项目(51378115)
Early Corrosion Behavior of Rebars Embedded in the Alkali Activated Slag Mortar
SHI Jinjie, DENG Chenhao, ZHANG Yamei
School of Materials Science & Engineering, Southeast University, Nanjing 211189, China
Abstract:
Mechanical strength development of three types of mortars(sea water mixing alkali activated slag mortar(SAAS), tap water mixing alkali activated slag mortar(TAAS) and cement slag blended mortar(CS)) after wetting drying cycles in artificial sea waters was investigated. The corrosion behaviors of two types of rebars, low carbon rebar(LC) and low alloy rebar(LA), in three types of mortars were tested via corrosion potential(Ecorr), linear polarization resistance(RP), and electrochemical impedance spectroscopy EIS measurements. The results show that, during the wetting drying cycles, SAAS and TAAS mortars have higher compressive strength than CS mortars. No significant difference of corrosion behavior can be observed for rebars in SAAS mortars and TAAS mortars. After 6 months of wetting drying cycles, it is indicated by increasing Rp and charge transfer resistance (Rct) values that both LC and LA in all mortars exhibit low corrosion rate.
Key words:  artificial sea water  alkali activated slag  rebar  electrochemical measurement