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引用本文:何娟,何廷树,杨长辉,王振军.碳化对碱矿渣水泥石干燥收缩的影响[J].建筑材料学报,2015,18(2):221-227
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碳化对碱矿渣水泥石干燥收缩的影响
何娟1, 何廷树1, 杨长辉2, 王振军3
1.西安建筑科技大学材料与矿资学院,陕西西安710055;2.重庆大学材料科学与工程学院,重庆400045;3.长安大学材料科学与工程学院,陕西西安710061
摘要:
为研究碳化行为对碱性胶凝材料干燥收缩的影响,以水玻璃或NaOH为碱组分,制备275×50mm碱矿渣水泥石试件,并测量275×1mm水泥石薄片在干缩条件与碳化条件下的直径变化率,以表征碱矿渣水泥石的干燥收缩与碳化收缩.结果表明:在(20±1)℃,相对湿度(70±5)%的条件下,以NaOH为碱组分的碱矿渣水泥石干燥收缩大于以水玻璃为碱组分的碱矿渣水泥石干燥收缩;碳化使硅酸盐水泥石的收缩增加,但未增加碱矿渣水泥石的收缩;碱当量适当提高有利于减小碱矿渣水泥石的干燥收缩与碳化收缩;以模数为12~15的水玻璃配制的碱矿渣水泥石干燥收缩与碳化收缩较小.
关键词:  碱矿渣水泥石  碳化  干燥收缩
DOI:103969/j.issn1007 9629201502007
分类号:
基金项目:陕西省教育厅自然科学专项项目(2013JK0923);陕西省自然科学基金资助项目(2013JQ6015);同济大学道路与交通工程教育部重点实验室开放基金资助项目(K201402)
Influence of Carbonation on Drying Shrinkage of Alkali Activated Slag Cement Stone
HE Juan1, HE Tingshu1, YANG Changhui2, WANG Zhenjun3
1.College of Material and Mineral Resources, Xian University of Architecture & Technology, Xian 710055, China;2.College of Materials Science and Engineering, Chongqing University, Chongqing 400045, China;3.School of Materials Science and Engineering, Changan University, Xian 710061, China
Abstract:
In order to study the effects of carbonation behavior of alkali activated cementitious material on drying shrinkage, alkali activated slag cement stone (AASS) specimen of 27. 5× 50mm was prepared by using water glass (WG) and sodium hydroxide (NH) as the alkali activator, and diameter change rate of 27. 5× 1mm cement sheets under drying and carbonation condition was measured to characterize the drying shrinkage and carbonation shrinkage of cement stone. The results show that in the temperature of (20±1)℃ and relative humidity of (70±5)%, drying shrinkage of AASS activated with NH is greater than that of AASS activated with WG. Carbonation increases the shrinkage of Portland cement stone, but does not increase the shrinkage of AASS. The appropriate raise of Na2O is helpful to reduce drying shrinkage and carbonization shrinkage of AASS. When water glass with the modulus of 1215 is used as the activator, drying shrinkage and carbonation shrinkage is relatively small.
Key words:  alkali activated slag cement stone  carbonation  drying shrinkage