凝灰岩机制骨料混凝土硫酸盐早期腐蚀研究
作者单位:

1.兰州理工大学;2.东南大学

基金项目:

国家自然科学基金项目(面上项目,重点项目,重大项目)


Study on sulfate early corrosion of tuff mechanism aggregate concrete
Author:
Affiliation:

1.Lanzhou University of Technology;2.Southeast University

Fund Project:

The National Natural Science Foundation of China(General Program,Key Program,Major Research Plan)

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    摘要:

    本文采用核磁共振(Nuclear Magnetic Resonance,NMR)技术对硫酸盐环境下机制骨料混凝土的早期劣化进行研究,并探究了水胶比、硫酸盐环境对机制骨料混凝土早期腐蚀的影响规律.结果表明:硫酸盐化学腐蚀和水化产物溶解是机制骨料混凝土早期性能劣化的主要原因,早期腐蚀产物以钙矾石和石膏为主;机制骨料混凝土初始孔隙率的降低可以抑制硫酸根离子的侵入和传输;腐蚀270d,硫酸盐溶液环境下混凝土多害孔和有害孔孔隙体积占比高于硫酸盐渍土环境2.15%和5.18%.

    Abstract:

    In order to more accurately simulate the early corrosion process of manufactured aggregate concrete in sulfate saline soils in northwest China.In this paper, the early deterioration of manufactured aggregate concrete under the action of sulfate saline soil is investigated by using nuclear magnetic resonance (NMR) technique.The effects of water-cement ratio, sulfate saline soil and salt solution on the early corrosion pattern of manufactured aggregate concrete were investigated.The results show that the main causes of early performance deterioration of manufactured aggregate concrete in sulfate saline soils are sulfate chemical corrosion and hydration product dissolution, and the early corrosion products are dominated by ettringite and gypsum. Initial total porosity of manufactured aggregate concrete decreases with decreasing water-cement ratio, fewer harmful pores are filled with corrosion products due to reduced porosity which inhibits the intrusion and transport of sulfate ions. Compared to saline soil environments,salt solution environment corrosion is more significant, the percentage of concrete porous and harmful pore pore volume increased by 2.15% and 5.18%, respectively.

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历史
  • 收稿日期:2024-12-07
  • 最后修改日期:2025-03-20
  • 录用日期:2025-03-21
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