电沉积法封堵混凝土裂缝的效果与机理研究
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同济大学材料学院

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Research on the Effect and Mechanism of Electrodeposition Method for Plugging Concrete Cracks
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Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education,Tongji University

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    摘要:

    采用电化学沉积方法(EDM)封堵钢筋混凝土裂缝,分别采用Cu、Zn和Fe阳极材料及CuSO4、ZnSO4和Fe2(SO4)3电解液,对比分析了电流密度、电解质溶液浓度和电沉积时间对裂缝表面闭合率、裂缝抗渗系数、离子在裂缝中的扩散深度、电极质量损失率等的影响,并通过XRD、SEM-EDS分析了电沉积产物组成及形貌,结果表明,愈合裂缝中的电沉积物结晶程度较高,形态各异;较低的电流密度和电解液浓度最有利于EDM的堵漏效果。

    Abstract:

    Cracks in reinforced concrete were sealed by a electrochemical deposition method (EDM). Three types of anode materials, Cu, Zn, Fe, and their corresponding CuSO4, ZnSO4, Fe2 (SO4) 3 electrolytes were used in EDM. The effects of current density, electrolyte solution concentration, and electrodeposition time on crack surface closure rate, crack impermeability coefficient, ion diffusion depth in cracks, and electrode quality loss rate, were analyzed in this paper. The composition of the electrodeposited products was analyzed by X-ray diffraction (XRD) and scanning electron microscopy combined with energy spectrum analysis(SEM-EDS). The morphology and results indicate that the degree of electrodeposits crystallization is relatively high, and their shapes vary Overall. Lower CD and lower SC is most beneficial for the plugging effect of DEM on concrete cracks.

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  • 收稿日期:2024-05-30
  • 最后修改日期:2024-09-10
  • 录用日期:2024-09-13
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