再生风积沙骨料表面疏水改性方法与机制研究
作者:
作者单位:

1.内蒙古大学 交通学院,内蒙古 呼和浩特 010021;2.内蒙古交通集团蒙通养护有限责任公司,内蒙古 呼和浩特 010060;3.内蒙古路桥集团有限责任公司,内蒙古 呼和浩特 010011

作者简介:

李 闯(1987—),男,内蒙古赤峰人,内蒙古大学讲师,博士. E-mail:lichuang8787@163.com

通讯作者:

张 宏(1978—),男,内蒙古乌兰察布人,内蒙古大学教授,博士生导师,博士. E-mail:zhanghong3537@126.com

中图分类号:

TU528.041

基金项目:

国家自然科学基金资助项目(51968053, 52268071);国家杰出青年科学基金资助项目(2023JQ03);内蒙古自治区自然科学基金资助项目(2024QN05023);内蒙古大学高层次人才科研启动基金项目(10000-22311201/008)


Surface Hydrophobic Modification Methods and Mechanisms of Recycled Aeolian Sand Aggregates
Author:
Affiliation:

1.College of Transportation, Inner Mongolia University, Huhhot 010021, China;2.Inner Mongolia Transportation Group Mengtong Maintenance Limited Liability Company, Huhhot 010060, China;3.Inner Mongolia Road and Bridge Group Limited Liability Company, Huhhot 010011, China

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    摘要:

    针对风积沙作为混凝土骨料使用时粒径小、比表面积大、吸水性强的问题,采用水泥胶结与表面疏水改性的方法,制备了大粒径表面疏水型再生风积沙骨料.结果表明:经硅烷偶联剂配合有机硅树脂改性的再生风积沙骨料,其吸水率明显降低,改性剂配比对再生风积沙骨料吸水率的影响较小;疏水改性不会降低再生风积沙骨料的强度以及再生风积沙骨料与水泥石间的黏结强度;使用表面改性再生风积沙骨料制备混凝土,其力学性能和工作性能明显改善;疏水改性可以优化再生风积沙骨料表面的微观结构,增大其表面浸润角.

    Abstract:

    To address the issue of small particle size, large specific surface area and high water absorption when aeolian sand was used as concrete aggregate, a large particle size surface hydrophobic recycled aeolian sand was prepared using cementation and surface hydrophobic modification. The results demonstrate that the water absorption of the recycled aeolian sand modified by a silane coupling agent with silicone resin is significantly reduced, and the modifier ratio has less influence on the water absorption of the recycled aeolian sand. Furthermore, hydrophobic modification does not reduce the strength of the recycled aeolian sand and the bond strength between recycled aeolian sand aggregate and cement stone. The mechanical properties and workability of concrete prepared with surface-modified recycled aeolian sand are significantly improved. The hydrophobic modification can optimize the surface microstructure of recycled aeolian sand and increase its surface contact angle.

    图1 风积沙的粒径分布Fig.1 Particle size distribution of aeolian sand
    图2 推出法测试再生风积沙材料与水泥石的黏结强度Fig.2 Push-out method for testing the bond strength of recycled aeolian sand material with cement paste
    图3 试件的吸水率Fig.3 Water absorption of specimens
    图4 试件的压碎值Fig.4 Crushing index of specimens
    图5 再生风积沙骨料与水泥石的黏结强度Fig.5 Bond strength between recycled aeolian sand and cement stone
    图6 试件的摊铺直径Fig.6 Extended diameter of specimens
    图7 骨料的表面浸润角Fig.7 Surface contact angle of aggregate
    图8 骨料的表面微观形貌Fig.8 Surface micromorphology of aggregate
    表 1 试件的配合比Table 1 Mix proportions of specimens
    表 2 试件的力学性能Table 2 Mechanical properties of specimens Unit: MPa
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引用本文

李闯,任永峰,张宏,吴平,杨亚雄.再生风积沙骨料表面疏水改性方法与机制研究[J].建筑材料学报,2025,28(3):270-275

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  • 收稿日期:2024-04-23
  • 最后修改日期:2024-06-12
  • 在线发布日期: 2025-04-06
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