赤泥复合固化剂固化粉土的路用性能及机理分析
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1.上海公路桥梁(集团)有限公司;2.中国矿业大学

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国家重点研发计划项目、“超大规模金属露天矿低碳开采技术与连续运载装备(典型应用示范类)”(2023YFC2907300)


Road Performance and Mechanism Analysis of Red Mud Composite Solidification Agent for Solidifying Silt
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1.Shanghai Road and Bridge( Group) Co.LTD;2.China University of Mining and Technology

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    摘要:

    以工业废弃物赤泥、电石渣和脱硫石膏组成的赤泥复合固化剂对低液限粉土进行固化,探究了固化粉土的力学性能(劈裂强度、无侧限抗压强度)和耐久性(水稳定性和干湿循环)的变化规律,并通过SEM扫描电镜试验和XRD衍射试验分析赤泥复合固化剂的固化机理。研究发现赤泥复合固化土的劈裂强度和无侧限抗压强度会随着固化土养护时间和固化剂掺量的增加而提高,水稳系数可从69.5%提高到82.4%;12次干湿循环后,赤泥复合固化土的强度损失率达到35.14%。赤泥复合固化剂掺入粉土中会发生水化反应,生成具有胶凝作用的C-S-H和C-A-H,同时C-A-H会与CaSO4生成钙矾石晶体。C-S-H和C-A-H包裹和填充土颗粒,钙矾石晶体穿插着土颗粒,使其成为一个整体,有效提高赤泥复合固化土的性能。

    Abstract:

    A red mud composite solidification agent composed of industrial waste red mud, calcium carbide slag, and desulfurization gypsum is selected to solidify the low liquid limit silt. The changes of mechanical properties (splitting strength, unconfined compressive strength) and durability (water stability and dry and wet cycle) of solidified silt were investigated. The curing mechanism of red mud composite curing agent was analyzed by SEM and XRD. The experimental results show that the red mud composite solidifying agent can significantly improve the road performance of silt. With the increase of solidifying agent dosage and curing age of solidified soil, the unconfined compressive strength and splitting emphasis of red mud composite solidified soil also increase, and the water stability coefficient can be increased from 69.5% to 82.4%. After 12 wet dry cycles, the strength loss rate of the red mud composite solidified soil reached 35.14%. When the red mud composite curing agent is incorporated into the silt, hydration reaction will occur to form C-S-H and C-A-H with gelling effect, and C-A-H will form ettringite crystals with CaSO4. C-S-H and C-A-H are wrapped and filled with soil particles, and ettringite crystals are interspersed with soil particles to form a whole, effectively improving the performance of red mud composite solidified soil.

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  • 收稿日期:2024-04-12
  • 最后修改日期:2024-07-25
  • 录用日期:2024-07-25
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