碳化对带裂缝混凝土中钢筋腐蚀的影响
作者:
作者单位:

1.青岛农业大学 建筑工程学院,山东 青岛 266109;2.宁波大学 土木工程与地理环境学院,浙江 宁波 315211

作者简介:

宋昌坤(2001—),男,山东青岛人,青岛农业大学硕士生. E-mail:15563951073@163.com

通讯作者:

柳俊哲(1964—),男,黑龙江哈尔滨人,青岛农业大学教授,博士生导师,博士. E-mail:junzheliu@163.com

中图分类号:

TU528.571

基金项目:

国家自然科学基金资助项目(52178223,51778302);浙江省教育厅科研项目(Y202146609)


Effect of Carbonization on Corrosion of Steel Bars in Concrete with Cracks
Author:
Affiliation:

1.College of Civil Engineering and Architecture, Qingdao Agricultural University, Qingdao 266109, China;2.School of Civil and Environment Engineering and Geography Science, Ningbo University, Ningbo 315211, China

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    摘要:

    为探究碳化作用下带裂缝混凝土中钢筋的腐蚀特征,通过控制裂缝参数,研究了带裂缝硬化水泥浆体的碳化规律,分析了碳化作用下带裂缝硬化水泥浆体中钢筋的腐蚀面积率、失重率和电化学腐蚀参数特征.结果表明:养护早期带裂缝水泥硬化浆体的裂缝宽度相较于水灰比对钢筋腐蚀的影响更为显著,养护后期裂缝宽度对钢筋腐蚀的影响仍逐渐增加,并占主导地位;碳化作用下带裂缝水泥硬化浆体的Nyquist图存在2个容抗弧,其中低频区容抗弧随着碳化龄期的增加逐渐收缩,钢筋表面双电层的传递电阻降低,钢筋开始脱钝;在一定的裂缝宽度范围内,较小的水灰比可以抑制硬化水泥浆体中的钢筋腐蚀.

    Abstract:

    In order to explore the corrosion characteristics of steel bars in cracked concrete under carbonation, the carbonation law of hardened cement pastes with cracks under carbonation was studied by controlling crack parameters, and the corrosion area rate, weight loss rate and electrochemical corrosion parameter characteristics of steel bars in hardened cement pastes with cracks were clarified. The results show that the crack width of the hardened cement paste with cracks in the early stage of curing has a more significant effect on the corrosion of steel bars than the water-cement ratio, and the influence of the crack width on the corrosion of steel bars gradually increases and plays a dominant role in the later stage of curing. There are two capacitive arcs in the Nyquist diagram of a cracked hardened cement paste under carbonization. As the age of carbonization increases, the capacitive arc resistance in the low-frequency region gradually shrinks, the transfer resistance of the electric double layer on the surface of the steel bar decreases, and the steel bar begins to remove the passivate film. Within a certain range of crack width, when the water-cement ratio is small, the corrosion of steel bars in hardened cement pastes can be suppressed.

    图1 用于测定Nyquist曲线和Tafel曲线的试件示意图Fig.1 Schematic digram for tast of Nyquist and Tafel curves(size:mm)
    图2 用于测定钢筋自然电位、失重率和腐蚀面积率的试件示意图Fig.2 Schematic diagram for test of spontaneous potential,corrosion area rate and weight loss rate of steel bars (size:mm)
    图3 裂缝面下不同距离处水泥硬化浆体的XRD图谱Fig.3 XRD patterns of hardened cement pastes located at different depths under crack surfaces
    图4 水灰比对带裂缝硬化水泥浆体碳化深度的影响Fig.4 Effect of water-to-water ratios on carbonation depth of hardened cement pastes with cracks
    图5 不同水灰比和裂缝宽度下各碳化龄期试件的交流阻抗Nyquist图Fig.5 EIS Nyquist curves of specimens with different water-to-cement ratios and crack depth after carbonation
    图6 不同裂缝宽度的硬化水泥浆体在碳化7、14、28、90 d时内部钢筋的Tafel曲线Fig.6 Tafel curves of steel bars in the hardened cement pastes with different crack widths after carbonization for 7, 14, 28,90 d
    图7 不同水灰比和裂缝宽度下硬化水泥浆体中钢筋自然电位随碳化龄期的变化趋势Fig.7 Change of spontaneous potential of steel bars in hardened cement pastes with different water-to-cement ratios and crackwidths
    图8 带裂缝水泥硬化浆体中钢筋腐蚀面积率和失重率Fig.8 Corrosion area rate and weight loss rate of steel bars in hardened cement paste with cracks
    表 1 钢筋电位与腐蚀概率之间的关系Table 1 Relationship between the potential and the corrosion probability of steel bars
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宋昌坤,张志成,江乐鑫,李晓珍,柳俊哲.碳化对带裂缝混凝土中钢筋腐蚀的影响[J].建筑材料学报,2025,28(3):276-282

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  • 收稿日期:2024-03-15
  • 最后修改日期:2024-09-09
  • 在线发布日期: 2025-04-06
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