RSM优化焚烧底灰胶凝材料及安全性评价
作者:
作者单位:

福建理工大学 生态环境与城市建设学院,福建 福州 350118

作者简介:

刘心中(1963—),男,山东淄博人,福建理工大学教授,硕士生导师,学士.E-mail:l74433527@qq.com

通讯作者:

刘心中(1963—),男,山东淄博人,福建理工大学教授,硕士生导师,学士.E-mail:l74433527@qq.com

中图分类号:

TU528.044

基金项目:

“十三五”国家重点研发计划项目(2019YFC1904103)


RSM Optimization of Incineration Bottom Ash Cementitious Material and Safety Evaluation
Author:
Affiliation:

School of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou 350118, China

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    摘要:

    为了将生活垃圾焚烧底灰(MSWI-BA)进行资源化利用,基于响应面中心复合试验法(RSM-CCD)研究了不同活性激发方式对经过预处理的MSWI-BA水泥胶砂试块28 d抗压强度的影响.结果表明:活性激发MSWI-BA胶凝材料具有较好的胶凝活性;采用RSM-CCD得到,掺10%MSWI-BA水泥胶砂试块在最佳试验条件下的28 d抗压强度计算值为46.04 MPa,实测值为46.15 MPa,二者符合较好,为MSWI-BA的资源化利用提供了一种解决方法;MSWI-BA胶凝材料的安全性较好,重金属浸出性能满足GB 30760—2014《水泥窑协同处置固体废物技术规范》的要求.

    Abstract:

    To recycle the municipal solid waste incineration bottom ash(MSWI-BA), the effects of different active excitation methods on the 28-day compressive strength of mortar test blocks prepared by pretreated MSWI-BA were studied by the method of response surface central composite test method(RSM-CCD). The results show that the MSWI-BA cementitious material has good cementitious activity by active excitation. The RSM-CCD test simulates that the 28-day compressive strength of the cement mortar test block with 10% MSWI-BA reaches 46.04 MPa under the optimal experimental conditions. Under this condition, the 28-day compressive strength of the cement mortar test block reaches 46.15 MPa, which is highly coincident with the predicted value. This method provides a solution for the resource utilization of MSWI-BA. Finally, the safety of the cementitious material is evaluated. The leaching performance of heavy metals meets the requirements of GB 30760—2014 Technical Specification for Coprocessing of Solid Waste in Cement Kiln.

    表 4 处理前后各类材料重金属浸出情况Table 4 Heavy metal leaching of various materials before and after treatment
    表 3 回归方程的方差分析表Table 3 Analysis of variance of regression equation
    图1 掺10%MSWI-BA水泥胶砂试块28 d抗压强度的残差图和实际值与预测值Fig.1 Residual diagram, actual value and predicted value of 28 d compressive strength of cement mortar test block mixed with 10% MSWI-BA
    图2 各因素对掺10%MSWI-BA水泥胶砂试块28 d抗压强度的交互作用Fig.2 Interaction of various factors on 28 d compressive strength of cement mortar test block mixed with 10% MSWI-BA
    图3 纯水泥胶砂试块和掺10% MSWI-BA胶砂试块的XRD图谱Fig.3 XRD patterns of OPC and OPC+10% MSWI-BA mortar test block
    图4 纯水泥胶砂试块的SEM照片Fig.4 SEM image of OPC mortar test block
    图5 掺10% MSWI-BA胶砂试块的SEM照片Fig.5 SEM image of OPC and OPC+10% MSWI-BA mortar test block
    图6 掺10% MSWI-BA胶砂试块和纯水泥胶砂试块的FTIR图谱Fig.6 FTIR spectra of OPC+10% MSWI-BA and OPC mortar test blocks
    表 1 RSM-CCD的设计因素及水平Table 1 Design factors and levels of RSM-CCD
    表 2 CCD的设计方案及结果Table 2 Design plans and results of CCD
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刘心中,郇冬冬,丘琛辉,张梦成,杨康.RSM优化焚烧底灰胶凝材料及安全性评价[J].建筑材料学报,2024,27(2):161-166

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  • 收稿日期:2023-03-07
  • 最后修改日期:2023-04-11
  • 在线发布日期: 2024-02-29
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