镁硅比和养护温度对硅酸镁水泥电磁性能的影响
作者:
作者单位:

1.北京工业大学 重庆研究院,重庆 401121;2.北京工业大学 城市建设学部,北京 100124;3.北京工业大学 理学部,北京 100124

作者简介:

李 悦(1972—),男,河北唐山人,北京工业大学教授,博士生导师,博士.E-mail:liyue@bjut.edu.cn

通讯作者:

李 悦(1972—),男,河北唐山人,北京工业大学教授,博士生导师,博士.E-mail:liyue@bjut.edu.cn

中图分类号:

TU525

基金项目:

重庆市自然科学基金资助项目(CSTB2022NSCQ-MSX1250);国家自然科学基金资助项目(52078015)


Effects of Magnesium-Silicon Ratio and Curing Temperature on Electromagnetic Properties of Magnesium Silicate Cement
Author:
Affiliation:

1.Chongqing Research Institute of Beijing University of Technology, Chongqing 401121,China;2.Faculty of Architecture, Civil and Transportation Engineering, Beijing University of Technology, Beijing 100124,China;3.Faculty of Science, Beijing University of Technology, Beijing 100124,China

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    摘要:

    采用波导法测定硅酸镁水泥的电磁性能,分析镁硅比和养护温度的影响,并基于微观测试结果进行机理分析.结果表明:提高养护温度可以显著增强硅酸镁水泥的早期强度;硅酸镁水泥的复介电常数实部随着镁硅比和养护温度的提高逐渐增大;提高养护温度使硅酸镁水泥的复介电常数虚部和损耗角正切值增大;与镁硅比相比,养护温度对硅酸镁水泥的透射率、反射率和吸收率的影响更为明显.微观测试结果显示含水量和孔结构对硅酸镁水泥的电磁性能有重要影响.

    Abstract:

    The electromagnetic properties of magnesium silicate cement were measured by waveguide method. The effects of magnesium-silicon ratio and curing temperature were analyzed and then the mechanism was analyzed based on the microscopic test results. The results show that the early age strength of magnesium silicate cement paste could significantly be enhanced by increasing the curing temperature. The real part of the complex permittivity increases with the increase of magnesium-silicon ratio and curing temperature. The imaginary part of the complex permittivity and the tangent of the loss angle increase by improving curing temperature. To compare with magnesium-silicon ratio, the transmittance, reflectivity and absorptivity are more obviously affected by the curing temperature. The microscopic test results indicate that the water content and pore structure have an important influence on the electromagnetic properties of magnesium silicate cement paste.

    图1 养护龄期为28 d时硅酸镁水泥复相对介电常数的实部、虚部和介电损耗角正切值的变化曲线Fig.1 Change curves of real part, imaginary part and dielectric loss tangent of complex relative dielectric constant of magnesium silicate cements cured for 28 d
    图2 养护龄期为28 d时硅酸镁水泥的电磁波透射率、反射率和吸收率Fig.2 Transmittivity, reflectivity and absorptivity of electromagnetic wave of magnesium silicate cements cured for 28 d
    图3 养护龄期为28 d时硅酸镁水泥的XRD和TG测试结果Fig.3 XRD and TG results of magnesium silicate cements cured for 28 d
    图4 养护龄期为28 d时硅酸镁水泥的SEM照片Fig.4 SEM images of magnesium silicate cements cured for 28 d
    图5 养护龄期为28 d时硅酸镁水泥的压汞测试结果Fig.5 MIP results of magnesium silicate cements cured for 28 d
    表 2 硅酸镁水泥中水和Mg(OH)2的含量Table 2 Content of water and Mg(OH)2 in magnesium silicate cements
    表 1 硅酸镁水泥的抗压强度Table 1 Compressive strengths of magnesium silicate cements
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引用本文

李悦,李洪文,金彩云,林辉,罗晓.镁硅比和养护温度对硅酸镁水泥电磁性能的影响[J].建筑材料学报,2024,27(2):139-145

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  • 收稿日期:2023-02-24
  • 最后修改日期:2023-04-26
  • 在线发布日期: 2024-02-29
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