碳化条件下循环流化床粉煤灰水化性能研究
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内蒙古工业大学

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TU528.09;X773

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国家自然科学(12262031);国家自然科学(52378348);内蒙古自治区科技计划项目(2021GG0344);内蒙古自治区自然科学基金青年(2023QN04016)


Study on Hydration Properties of Circulating Fluidized Bed Fly Ash Under Carbonation Conditions
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College of Civil Engineering, Inner Mongolia University of Technology

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    摘要:

    工业固废的资源化利用是实现碳减排和能源利用的有效手段. 本研究以循环流化床粉煤灰(CFBFA)和脱硫石膏(FGD)为矿物掺合料制备胶砂试件,通过碳化试验、胶砂强度试验和XRD、SEM-EDS微观测试手段,探究胶砂试件在碳化条件下的固碳能力、力学性能和反应机理. 结果表明:固废的掺入增加了浆体孔隙,提高了钙源含量,使固废胶砂的CO2吸收量显著提高. 碳化养护后胶砂的力学性能显著提高,消除了高硫带来的膨胀性问题. 运用该工艺可将内蒙古地区工业固废利用率提高至36.5%.

    Abstract:

    The resource utilization of industrial solid waste is an effective means to achieve carbon emission reduction and energy utilization. This study used circulating fluidized bed fly ash ( CFBFA ) and desulfurization gypsum ( FGD ) as mineral admixtures to prepare mortar specimens. The carbonation test, mortar strength test, XRD, and SEM-EDS microscopic test methods were used to explore the carbon sequestration capacity, mechanical properties, and reaction mechanism of mortar specimens under carbonation conditions. The results show that the incorporation of solid waste increases the slurry's porosity the calcium source's content, and significantly increases the CO2 absorption of solid waste mortar. The mechanical properties of the mortar are significantly improved after carbonation curing, and the expansion problem caused by high sulfur is eliminated. The utilization rate of industrial solid waste in Inner Mongolia can be increased to 36.5 % by using this process.

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  • 收稿日期:2023-11-16
  • 最后修改日期:2024-02-18
  • 录用日期:2024-03-11
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