摩尔比对MMOS水泥力学性能和变形行为的影响及机理
作者:
作者单位:

1.宁波大学 土木工程与地理环境学院, 浙江 宁波 315211;2.青岛农业大学 建筑工程学院,山东 青岛 266109

作者简介:

巴明芳(1975—),女,山东滨州人,宁波大学教授,博士生导师,博士.E-mail:bamingfang@nbu.edu.cn

通讯作者:

柳俊哲(1964—),男,黑龙江五常人,青岛农业大学教授,博士生导师,博士.E-mail:junzheliu@163.com

中图分类号:

TU526

基金项目:

国家自然科学基金资助项目(51978346)


Effect of Molar Ratio on Mechanical Properties and Deformation Behavior of Modified Magnesium Oxysulfate Cement and Its Mechanism
Author:
Affiliation:

1.School of Civil Engineering and Geographical Environment, Ningbo University, Ningbo 315211, China;2.College of Architecture Engineering,Qingdao Agricultural University,Qingdao 266109,China

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    摘要:

    研究了原材料摩尔比(n(MgO)∶n(MgSO4)∶n(H2O))对改性硫氧镁(MMOS)水泥力学性能和变形行为的影响,并采用X射线衍射仪(XRD)、扫描电镜(SEM)、傅里叶变换红外光谱(FTIR)及热重分析(TG)等测试技术对其机理进行分析.结果表明:MMOS水泥的抗压强度和抗折强度随着水硫比和氧硫比的提高均呈提升趋势.其中原材料摩尔比为10∶1∶12时,水泥力学性能最优.不同摩尔比MMOS水泥在56 d龄期内均呈膨胀变形,其中总变形随水硫比和氧硫比的提高呈减小趋势;自收缩变形随水硫比的提高而减小,随氧硫比的提高呈先增后减趋势.这主要是由于硬化后不同摩尔比MMOS水泥中的水化产物Mg(OH)2和5·1·7相(5Mg(OH)2·MgSO4·7H2O)含量各有不同.当Mg(OH)2含量减少,而5·1·7相含量增加时,MMOS水泥的膨胀变形量降低,同时其抗折强度和抗压强度有所提升.

    Abstract:

    The effect of the molar ratio(n(MgO)∶n(MgSO4)∶n(H2O)) in the raw materials on the mechanical properties and deformation characteristics of modified magnesium oxysulfide(MMOS) cement was studied, and the mechanism was analyzed by testing techniques, such as X-ray diffraction(XRD), scanning electron microscope(SEM), Fourier transform infrared spectroscopy(FTIR) and thermogravimetric analysis(TG). The results show that the compressive strength and flexural strength of MMOS cement matrix shows an increasing trend with the increase of water-sulfur ratio and oxygen-sulfur ratio. The specimen with a molar ratio of 10∶1∶12 has the highest compressive and flexural strength. The deformation of MMOS cement specimens with different molar ratios during the period from completion of pouring to 56 days of curing is mainly expansion deformation. The total deformation of MMOS cement specimens shows a decreasing trend with the increase of water-sulfur ratio and oxygen-sulfur ratio, while the autogenous deformation shows a decreasing trend with the increase of water-sulfur ratio and a first increasing and then decreasing trend with the increase of oxygen-sulfur ratio. The MMOS cement specimens with different molar ratios exhibit differences in expansion deformation, mainly due to the different contents of hydration products Mg(OH)2, 5·1·7 phase (5Mg(OH)2·MgSO4·7H2O) and unreacted MgO phase in the hardened matrix. When the content of Mg(OH)2 decreases and the content of 5·1·7 phase increases, the expansion deformation phenomenon of MMOS cement specimens weakens, while their flexural strength and compressive strength are improved.

    表 1 七水硫酸镁的化学组成Table 1 Chemical composition(by mass) of magnesium sulfate heptahydrate Unit:%
    表 2 轻烧氧化镁的氧化物组成Table 2 Oxide composition(by mass) of light-burned magnesium oxide Unit:%
    表 3 MMOS水泥净浆配合比Table 3 Mix proportions of modified magnesium oxysulfate cement pastes
    表 5 不同氧硫比MMOS水泥试样的Mg(OH)2和5Mg(OH)2·MgSO4含量Table 5 Mg (OH)2 and 5Mg (OH)2·MgSO4 contents in MMOS cement samples with different oxygen-sulfur ratios
    图1 轻烧氧化镁的XRD图谱Fig.1 XRD pattern of light-burned magnesium oxide
    图2 轻烧氧化镁的粒度分布Fig.2 Particle size distribution of light-burned magnesium oxide
    图3 水硫比对MMOS水泥试件抗折强度和抗压强度的影响Fig.3 Effect of water-sulfur ratio on flexural strength and compressive strength of MMOS cement specimens
    图4 氧硫比对MMOS水泥试件抗折强度和抗压强度的影响Fig.4 Effect of oxygen-sulfur ratio on flexural strength and compressive strength of MMOS cement specimens
    图5 水硫比对MMOS水泥试件变形特征的影响Fig.5 Effect of water-sulfur ratio on deformation characteristic of MMOS cement specimens
    图6 氧硫比对MMOS水泥试件变形特征的影响Fig.6 Effect of oxygen-sulfur ratio on deformation characteristic of MMOS cement specimens
    图7 不同水硫比MMOS水泥试样的红外光谱Fig.7 FTIR spectra of MMOS cement samples with different water-sulfur ratios
    图8 不同氧硫比MMOS水泥试样的红外光谱Fig.8 FTIR spectra of MMOS cement samples with different oxygen-sulfur ratios
    图9 不同水硫比MMOS水泥试样的TG-DTG曲线Fig.9 TG-DTG curves of MMOS cement samples with different water-sulfur ratios
    图10 不同氧硫比MMOS水泥试样的TG-DTG曲线Fig.10 TG-DTG curves of MMOS cement samples with different oxygen-sulfur ratios
    图11 不同水硫比MMOS水泥试样的XRD图谱Fig.11 XRD patterns of MMOS cement samples with different water-sulfur ratios
    图12 不同氧硫比MMOS水泥试样的XRD图谱Fig.12 XRD patterns of MMOS cement samples with different oxygen-sulfur ratios
    图13 不同水硫比MMOS水泥试样的SEM照片Fig.13 SEM images of MMOS cement samples with different water-sulfur ratios
    图14 不同氧硫比MMOS水泥试样的SEM照片Fig.14 SEM images of MMOS cement samples with different oxygen-sulfur ratios
    表 4 不同水硫比MMOS水泥试样的Mg(OH)2和5Mg(OH)2·MgSO4含量Table 4 Mg (OH)2 and 5Mg (OH)2·MgSO4 contents in MMOS cement samples with different water-sulfur ratios
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巴明芳,马哲洋,纪璐鑫,崔嘉铭,柳俊哲.摩尔比对MMOS水泥力学性能和变形行为的影响及机理[J].建筑材料学报,2024,27(8):733-743

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  • 收稿日期:2023-10-11
  • 最后修改日期:2023-12-16
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