碳酸水环境下隧道水泥基材料的抗侵蚀特性
作者:
作者单位:

1.中国铁道科学研究院 研究生部,北京 100081;2.中国铁道科学研究院集团有限公司 高速铁路轨道系统全国重点实验室,北京 100081;3.中国铁道科学研究院集团有限公司 铁道建筑研究所,北京 100081;4.北京科技大学 土木与资源工程学院,北京 100083

作者简介:

李 康(1994—),男,山西原平人,中国铁道科学研究院博士生.E-mail:likangbkd1994@163.com

通讯作者:

刘娟红(1966—),女,江苏苏州人,北京科技大学教授,博士生导师,博士.E-mail:juanhong1966@hotmail.com

中图分类号:

TU528.041

基金项目:

中国铁道科学研究院集团有限公司科研项目(2021YJ059);国家自然科学基金资助项目(52293430)


Erosion Characteristics of Tunnel Cement-Based Materials in Carbonated Water
Author:
Affiliation:

1.Postgraduate Department, China Academy of Railway Sciences, Beijing 100081, China;2.State Key Laboratory for Track System of High-Speed Railway, China Academy of Railway Science Co., Ltd., Beijing 100081, China;3.Railway Engineering Researd Institute, China Academy of Railway Sciences Co., Ltd., Beijing 100081, China;4.College of Civil and Resource Engineering, University of Science and Technology Beijing, Beijing 100083, China

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    摘要:

    对比了多种水泥基材料在碳酸水加速侵蚀前后的抗压强度、材料内部的物相迁移和孔结构特征.结果表明:碳酸水侵蚀后水泥基材料强度的发展受到限制,Ca(OH)2和CaCO3含量同时降低,孔径粗化且有害孔的比例增大;以水化硅酸钙凝胶和Ca(OH)2为主要水化产物的胶凝体系最容易受到碳酸水的侵蚀,且Ca(OH)2含量越高,水泥基材料抗碳酸水侵蚀的能力越弱;以钙矾石为主要水化产物的胶凝体系抗碳酸水侵蚀的能力明显增强.

    Abstract:

    Compressive strength,internal phase migration and pore structure characteristics of various cementitious materials before and after accelerated erosion by carbonated water were compared. The results show that the strength development is limited after carbonated water erosion, the Ca(OH)2 and CaCO3 contents are reduced at the same time, the pore size becomes larger and the proportion of harmful pores increases. The cementitious system with hydrate calcium silicate gel and Ca(OH)2 as the main hydration products is most vulnerable to carbonated water erosion, and the cement-based material with higher content of Ca(OH)2 has weaker resistance to carbonated water. The resistance of carbonated water erosion of the cementitious system with ettringite as the main hydration product is significantly enhanced.

    表 4 净浆中晶相和非晶相的含量Table 4 Mass fractions of crystalline and amorphous phase in cement pastes
    表 1 普通硅酸盐水泥和硫铝酸盐水泥的物理性能Table 1 Physical properties of ordinary Portland cement and sulfoaluminate cement
    表 3 净浆试块的配合比Table 3 Mix proportions of cement paste specimens
    图1 碳酸水加速侵蚀试验的原理与仪器Fig.1 Schematic diagram and instrument for carbonated water accelerated erosion test
    图2 净浆试件在碳酸水侵蚀前后的抗压强度Fig.2 Compressive strength of cement paste specimens before and after carbonated water erosion
    图3 净浆试件碳酸水侵蚀28 d与清水浸泡28 d后的抗压强度Fig.3 Compressive strength of cement paste specimens after 28 d in carbonated water and in clear water
    图4 碳酸水侵蚀前后及清水浸泡组净浆的XRD图谱Fig.4 XRD patterns of cement paste specimens in carbonated water and in clear water
    图5 碳酸水侵蚀前后及清水浸泡组净浆的TG-DTG曲线Fig.5 TG-DTG curves of cement pastes in carbonated water and in clear water
    图6 A2组净浆的热重曲线与Ca(OH)2和CaCO3含量Fig.6 TG curves and mass fractions of Ca(OH)2 and CaCO3 in A2
    图7 碳酸水侵蚀前后及清水浸泡组净浆总孔隙率Fig.7 Total porosity of cement paste specimens in carbonated water and in clear water
    图8 碳酸水侵蚀前后及清水浸泡组净浆累积孔体积分布曲线Fig.8 Cumulative pore volume curves of cement paste specimens in carbonated water and in clear water
    图9 碳酸水侵蚀前后净浆的微分孔径曲线Fig.9 Differential pore size curves of cement paste specimens in carbonated water and in clear water
    图10 碳酸水侵蚀前后A2组净浆的孔隙结构Fig.10 Pore structure of A2 cement paste in carbonated water and in clear water
    表 2 胶凝材料化学组成Table 2 Chemical compositions(by mass) of cementitious materials
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李康,邹敏,王希,谢永江,刘娟红.碳酸水环境下隧道水泥基材料的抗侵蚀特性[J].建筑材料学报,2024,27(5):408-417

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  • 收稿日期:2023-06-01
  • 最后修改日期:2023-07-01
  • 在线发布日期: 2024-06-11
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