碳酸钙晶须对碱矿渣胶凝材料的减缩增强作用
作者:
作者单位:

1.安徽建筑大学 安徽省先进建筑材料重点实验室, 安徽 合肥 230022;2.同济大学 材料科学与工程学院,上海 201804

作者简介:

赵 俊(1998—),男,江苏扬州人,安徽建筑大学硕士生.E-mail:junzhao1998@126.com

通讯作者:

王爱国(1978—),男,安徽合肥人,安徽建筑大学教授,博士生导师,博士.E-mail:wag3134@126.com

中图分类号:

TQ427.2+6

基金项目:

国家自然科学基金资助项目(52278236, 52172013);安徽省高校优秀科研创新团队项目(2022AH010017);安徽省重点研究与开发计划项目(202104a07020018);安徽建筑大学科研储备库培育项目(2021XMK02)


Effect of Calcium Carbonate Whisker on Shrinkage Reduction and Reinforcement of Alkali-Activated Slag Cementitious Materials
Author:
Affiliation:

1.Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei 230022, China;2.School of Materials Science and Engineering, Tongji University, Shanghai 201804, China

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    摘要:

    针对碱矿渣胶凝材料易收缩开裂等问题,采用一种新型微米级纤维——碳酸钙晶须对碱矿渣胶凝材料进行减缩增强,研究了碳酸钙晶须掺量对碱矿渣胶凝材料流变性能、抗压强度和干燥收缩的影响,并探究其显微增强机理.结果表明:微米级碳酸钙晶须的掺入对碱矿渣胶凝材料流动性影响较小,当碳酸钙晶须掺量为3%时,其新拌浆体塑性黏度为12.33 Pa·s,较未掺碳酸钙晶须的对照组仅增长14.48%,其硬化浆体28 d抗压强度可达105.8 MPa;碱矿渣胶凝材料的干燥收缩率随着碳酸钙晶须掺量的增加而降低,当碳酸钙晶须掺量为5%时,其28 d干燥收缩率仅有0.87%,较未掺碳酸钙晶须的对照组降低32.56%;碳酸钙晶须与基体紧密结合,在基体受力破坏时分散其所受应力,提升了碱矿渣胶凝材料的力学性能;碳酸钙晶须在体系内部的桥接作用能够有效延缓碱矿渣胶凝材料微裂纹的形成与扩展,在一定程度上遏制了宏观裂纹的发展.

    Abstract:

    In response to the problem of shrinkage and cracking of alkali-activated slag cementitious material, a new type of micrometer sized fiber—calcium carbonate whisker was used to reduce drying shrinkage and enhance mechanical properties of alkali-activated slag cementitious material. The effects of different contents of calcium carbonate whiskers on the rheological properties, compressive strength and drying shrinkage of alkali-activated slag cementitious material were studied, and the micro reinforcement mechanism was explored. The results show that the addition of micrometer sized calcium carbonate whisker has little effect on the fluidity of alkali-activated slag cementitious material. When the calcium carbonate whiskers’ content is 3%, the plastic viscosity of the freshly mixed slurry is 12.33 Pa·s, which is only 14.48% higher than the control group without calcium carbonate whiskers. The 28 d compressive strength of the hardened slurry reaches 105.8 MPa. The drying shrinkage rate of alkali-activated slag cementitious material decreases with the increase of calcium carbonate whiskers’ content. When the calcium carbonate whiskers’ content is 5%, its 28 d drying shrinkage rate is only 0.87%, which is 32.56% lower than that of alkali-activated slag cementitious material without calcium carbonate whiskers. Calcium carbonate whiskers are tightly combined with the matrix, dispersing the stress on the matrix when it is subjected to stress and improving the mechanical properties of alkali-activated slag cementitious material. The bridging effect of calcium carbonate whisker can effectively delay the formation and propagation of microcracks in alkali-activated slag cementitious material, and the development of macroscopic crack can be restrained to a certain extent.

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引用本文

赵俊,王爱国,张祖华,刘开伟,孙道胜.碳酸钙晶须对碱矿渣胶凝材料的减缩增强作用[J].建筑材料学报,2024,27(4):359-365

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  • 收稿日期:2023-05-08
  • 最后修改日期:2023-06-09
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  • 在线发布日期: 2024-05-11
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