磷石膏制备免烧人造骨料及其性能
作者:
作者单位:

安徽工业大学 冶金工程学院,安徽 马鞍山 243002

作者简介:

马文青(1997—),女,河北张家口人,安徽工业大学硕士生.E-mail:1968327142@qq.com

通讯作者:

李灿华(1979—),男,安徽太湖人,安徽工业大学教授,硕士生导师,博士.E-mail:licanhua1979@163.com

中图分类号:

TU526


Preparation of Calcined-Free Artificial Aggregate from Phosphogypsum and Its Performance
Author:
Affiliation:

Metallurgical Engineering School, Anhui University of Technology, Maanshan 243002, China

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    摘要:

    以磷石膏为原材料,利用碱激发技术制备人造骨料,并研究不同配合比对人造骨料性能的影响.结果表明:当水添加量为10%、水玻璃添加量(以Na2O含量计)为3%、成型压力为63 MPa、养护时间为28 d、水泥掺量为30%时,人造骨料的抗压强度达到25.16 MPa,吸水率为15.21%,堆积密度为1 156.4 kg/m3;骨料中的钙矾石等水化产物增强了人造骨料的强度.

    Abstract:

    Artificial aggregates were prepared from phosphogypsum as raw material by using alkali excitation technology. The effects of different ratios on the properties of artificial aggregates were studied. The results show that when the water addition is 10% and sodium silicate addition (calculated as Na2O content) is 3%, molding pressure is 63 MPa, curing time is 28 days, and cement content is 30%, the compressive strength of the artificial aggregate reaches 25.16 MPa, water absorption rate reaches 15.21%, and bulk density reaches 1 156.4 kg/m3. The hydration products such as ettringite in the aggregate enhance the strength of artificial aggregates.

    表 2 磷石膏-水泥人造骨料浸出重金属的质量浓度Table 2 Mass concentration of heavy metal leaching from PG-cement artificial aggregates
    表 1 磷石膏的化学组成Table 1 Chemical composition(by mass) of phosphogypsum
    图1 磷石膏的粒度分布Fig.1 Particle size distribution of phosphogypsum
    图2 水添加量对磷石膏人造骨料抗压强度的影响Fig.2 Effect of water addition on compressive strength of PG artificial aggregates
    图3 水玻璃添加量对磷石膏人造骨料抗压强度的影响Fig.3 Effect of sodium silicate addition on compressive strength of PG artificial aggregates
    图4 成型压力对磷石膏人造骨料抗压强度的影响Fig.4 Effect of molding pressure on compressive strength of PG artificial aggregates
    图5 水泥掺量对磷石膏-水泥人造骨料抗压强度的影响Fig.5 Effect of cement content on compressive strength of PG-cement artificial aggregates
    图6 水泥掺量对磷石膏-水泥人造骨料吸水率的影响Fig.6 Effect of cement content on water absorption of PG-cement artificial aggregates
    图7 水泥掺量对磷石膏-水泥人造骨料堆积密度的影响Fig.7 Effect of cement content on bulk density of PG-cement artificial aggregates
    图8 人造骨料的XRD图谱Fig.8 XRD patterns of artificial aggregates
    图9 磷石膏-水泥人造骨料的SEM-EDS分析Fig.9 SEM-EDS analysis of PG-cement artificial aggregates
    图10 磷石膏-水泥人造骨料的FTIR图谱Fig.10 FTIR spectra of PG-cement artificial aggregates
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马文青,李子木,李灿华,章蓝月,李明晖.磷石膏制备免烧人造骨料及其性能[J].建筑材料学报,2024,27(4):375-380

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  • 收稿日期:2023-04-06
  • 最后修改日期:2023-09-18
  • 在线发布日期: 2024-05-11
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