海洋大气环境中Q370qENH耐候钢的应力腐蚀演化
作者:
作者单位:

1.中南大学 土木工程学院,湖南 长沙 410075;2.中南大学 高速铁路建造技术国家工程研究中心,湖南 长沙 410075;3.山东铁路投资控股集团有限公司,山东 济南 250102

作者简介:

余玉洁(1990—),女,江西南昌人,中南大学教授,博士生导师,博士.E-mail:yujiecsu@csu.edu.cn

通讯作者:

余玉洁(1990—),女,江西南昌人,中南大学教授,博士生导师,博士.E-mail:yujiecsu@csu.edu.cn

中图分类号:

U24;TG172.3

基金项目:

国家自然科学基金资助项目(52278231);山东省交通运输行业重点科研项目(2021-MS4-097);山东省交通运输厅科技计划(2021B103);湖南省自然科学基金资助项目(2022JJ20073)


Stress Corrosion Evolution of Q370qENH Weathering Steel in Marine Atmosphere Environment
Author:
Affiliation:

1.School of Civil Engineering, Central South University, Changsha 410075, China;2.National Engineering Research Center of High-Speed Railway Construction Technology, Central South University, Changsha 410075, China;3.Shandong Railway Investment Holding Group Company Limited, Jinan 250102, China

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    摘要:

    采用周期性干湿交替盐雾加速腐蚀试验来模拟海洋性大气腐蚀环境,研究了应力作用下Q370qENH耐候钢的腐蚀速率、锈层发育与物相组成、锈坑形貌以及损伤拉伸性能.结果表明:相较于无应力腐蚀,应力腐蚀显著提升了Q370qENH表面的腐蚀活性,加快了Q370qENH的腐蚀,同时在一定程度上延缓了稳定性锈层的生成,并进一步削减了Q370qENH的强度;无论是否存在应力,Q370qENH在盐雾环境中最后均未生成较为稳定的锈层保护层;在高氯海洋性大气腐蚀环境中,Q370qENH并未表现出优越的抗腐蚀性能,不建议免涂装使用;Q370qENH腐蚀后的各项性能仍处于较高水平.

    Abstract:

    The corrosion resistance of Q370qENH weathering steel was investigated by using periodic dry/wet alternating salt spray accelerated corrosion tests to simulate marine atmospheric corrosion environment. A comprehensive analysis was performed with analyzing the corrosion rate, rust layer development and phase composition, rust pit morphology and damage tensile property, including corrosive mechanism and characterization. The results show that compared with stress free corrosion, the stress corrosion can significantly improve the corrosion activity of Q370qENH’s surface, thus speeding up the corrosion rate, delaying the formation of stable rust layer to a certain extent and further reducing Q370qENH’s strength. However, no matter whether there is stress or not, the stable protective layer is not formed in the salt spray environment. Q370qENH does not show excellent corrosion resistance in high chloride atmosphere, in which corrosion environment, Q370qENH is not recommended to be used without coating. But Q370qENH still presents a good mechanical properties when with a high level of corrosion.

    表 1 Q370qENH的化学组成Table 1 Chemical composition of Q370qENH
    图1 腐蚀试件及应力加载示意图Fig.1 Corrosion specimens and stress loading diagram(size: mm)
    图2 试件腐蚀量及腐蚀速率随腐蚀时间的变化Fig.2 Change of corrosion amount and corrosion rate of samples with corrosion time
    图3 锈层的发育情况Fig.3 Development of rust layer
    图4 应力作用下经历35个腐蚀循环后锈层的剥落Fig.4 Rust layer peeled off after 35 stress corrosion cycles
    图5 锈层的胶黏测试结果Fig.5 Adhesive test result of rust layer
    图6 锈层的XRD图谱Fig.6 XRD patterns of rust layers
    图7 干湿交替腐蚀下钢材的锈蚀流程图Fig.7 Rusting flow chart of steel corrosion under dry/wet alternating corrosion
    图8 除锈后试件的表面形貌Fig.8 Surface morphology of specimens after rust removal
    图9 试件的静力拉伸结果Fig.9 Static tensile results of specimens
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引用本文

余玉洁,罗永琪,孙洪斌,胡春建,朱志辉.海洋大气环境中Q370qENH耐候钢的应力腐蚀演化[J].建筑材料学报,2023,26(12):1271-1278

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  • 收稿日期:2023-03-31
  • 最后修改日期:2023-05-22
  • 在线发布日期: 2024-01-08
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