不同古建筑灰浆加固剂的修复效果研究
作者:
作者单位:

北京化工大学 材料科学与工程学院,北京 100029

作者简介:

陈绍华(1994—),男,天津人,北京化工大学硕士生. E-mail: 735232264@qq.com

通讯作者:

王菊琳(1966—),女,江苏溧阳人,北京化工大学教授,博士生导师,博士.E-mail: julinwang@126.com

中图分类号:

TU52


Repair Effect of Various Consolidants for Ancient Building Lime Plaster
Author:
Affiliation:

Institute of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

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    摘要:

    针对古建筑中需原位保护的灰浆,选用磷酸氢二铵(DAP)、正硅酸乙酯和纳米氢氧化钙溶液配制了6种加固剂,从相容性和有效性两方面评估其对灰浆的加固效果.结果表明:综合性能最佳的加固剂为添加5%(体积分数)无水乙醇的0.1 mol/L的 DAP溶液;加固后灰浆生成化学性质更稳定的羟基磷灰石矿物,其表面致密性有所提高,色度变化符合文物保护要求,残留N、P元素的风险小,加固剂的相容性好;加固后灰浆的毛细吸水能力、表面黏聚力、动弹性模量及抗压强度均得到显著改善,加固剂的有效性好.

    Abstract:

    Six kinds of consolidants for the lime plaster that needed in-situ protection in ancient building were prepared by diammonium phosphate(DAP), ethyl orthosilicate and nano-calcium hydroxide solution, and their consolidation effects were evaluated by compatibility and effectiveness. The results show that the consolidant with the best comprehensive performance is 0.1 mol/L DAP solution with 5%(by volume) ethanol. The lime plaster consolidated by the above consolidant generates more chemically stable hydroxyapatite mineral, hence its surface density increases, its color changes in line with the requirement of cultural relic protection, and the risk of residual N and P elements is small. It indicates that the compatibility of the consolidant is good. The capillary water absorption capacity, surface cohesion, dynamic elastic modulus and compressive strength of the above consolidated lime plaster are significantly improved, which indicates the effectiveness of the consolidant.

    表 1 加固剂配比Table 1 Mix proportions of consolidants
    图1 吸水率测试装置示意图Fig.1 Schematic diagram of water absorption test device (size: cm)
    图2 未处理及经不同加固剂处理后灰浆试样的FTIR图谱Fig.2 FTIR spectra of untreated lime plaster and lime plasters treated by various consolidants
    图3 未经处理及经不同加固剂处理后灰浆试样表面的SEM图片Fig.3 SEM images of surfaces of untreated lime plaster and lime plasters treated by various consolidants
    图4 经不同加固剂处理后的灰浆试样表面的色度变化Fig.4 Color changes of surfaces of lime plasters treated by various consolidants
    图5 未处理及经不同加固剂处理后灰浆试样的吸水性曲线Fig.5 Water absorption curves of untreated lime plaster and lime plasters treated by various consolidants
    图6 未处理及经不同加固剂处理后灰浆试样的透明胶带试验结果Fig.6 Results of scotch tape test on untreated lime plaster and lime plasters treated by various consolidants
    图7 未处理及经不同加固剂处理后灰浆试样的动弹性模量增长率及抗压强度Fig.7 Increase ratios of dynamic elastic modulus and compressive strengths of untreated lime plaster and lime plasters treated by various consolidants
    表 2 未处理及经不同加固剂处理后灰浆试样的表面吸水系数Table 2 Surface water absorption coefficients of untreated lime plaster and lime plasters treated by various consolidants
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陈绍华,王菊琳.不同古建筑灰浆加固剂的修复效果研究[J].建筑材料学报,2023,26(5):530-537

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  • 收稿日期:2022-04-17
  • 最后修改日期:2022-12-02
  • 在线发布日期: 2023-06-08
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