钢筋阻锈剂在碳化钢筋混凝土中的阻锈作用
作者:
作者单位:

1.青岛农业大学 建筑工程学院,山东 青岛 266109;2.宁波大学 土木与环境工程学院,浙江 宁波 315211

作者简介:

郭 群(1997—),女,山东高密人,青岛农业大学硕士生.E-mail: guoqun0302@163.com

通讯作者:

柳俊哲(1964—),男,黑龙江哈尔滨人,青岛农业大学教授,博士生导师,博士.E-mail: junzheliu@163.com

中图分类号:

TU528.1

基金项目:

国家自然科学基金资助项目(52178223,51778302)


Effect of Steel Bar Corrosion Inhibitors in Carbonated Reinforced Concrete
Author:
Affiliation:

1.College of Architecture Engineering, Qingdao Agricultural University, Qingdao 266109, China;2.School of Civil and Environmental Engineering, Ningbo University, Ningbo 315211, China

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    摘要:

    研究了阳极型阻锈剂Na2CrO4和Na2MoO4、阴极型阻锈剂苯并三氮唑(BTA)和N,N-二甲基乙醇胺(DMEA),以及由这些阻锈剂复配得到的复合型阻锈剂在碳化钢筋混凝土中的阻锈作用,通过钢筋的自然电位、腐蚀面积率、失重率和电化学法研究了钢筋在碳化混凝土中的腐蚀程度和腐蚀速率.结果表明:碳化混凝土中钢筋的抗腐蚀性随着阻锈剂掺量的增加而提高,随着碳化时间的增加而降低;复掺1.00%Na2MoO4和1.00%BTA时,碳化混凝土中钢筋的腐蚀程度最小,阻锈剂的阻锈效果最佳;复合型阻锈剂延缓钢筋腐蚀速率的效果优于单一型阻锈剂,同一掺量条件下,复掺Na2MoO4和BTA阻锈剂延缓钢筋腐蚀速率的效果最佳.

    Abstract:

    The effect of different types of corrosion inhibitors, such as anodic corrosion inhibitors Na2CrO4 and Na2MoO4, cathodic corrosion inhibitors benzotriazole (BTA) and N,N-dimethylethanolamine (DMEA), and their combination on the corrosion inhibition of steel bars in carbonated reinforced concrete was investigated. The corrosion degree and corrosion rate of steel bars in carbonated reinforced concrete were evaluated by spontaneous potential, corrosion area percent and mass loss percent of steel bars and electrochemical method. The results show that the corrosion resistance of steel bars in carbonated reinforced concrete increases with the increase of corrosion inhibitor content and decreases with the increase of carbonation time. The corrosion degree of steel bars in carbonated reinforced concrete with 1.00% Na2MoO4 and 1.00% BTA addition is the least among all the specimens and the corrosion inhibition effect is the best. The effect of compound corrosion inhibitor on retarding corrosion rate of steel bars is better than that of single corrosion inhibitor, and the effect of adding the combination of Na2MoO4 and BTA is the best.

    表 2 HPB235光圆钢筋的化学组成Table 2 Chemical composition of HPB235 plain round steel bar
    表 1 水泥的化学组成Table 1 Chemical composition of cement
    图1 混凝土和水泥净浆试件的尺寸和构造示意图Fig.1 Schematic diagram of dimension and structure of concrete and cement paste specimens(size: mm)
    图2 碳化钢筋混凝土中钢筋的自然电位Fig.2 Spontaneous potentials of steel bars in carbonated reinforced concrete
    图3 碳化钢筋混凝土中钢筋的腐蚀面积率和失重率Fig.3 Corrosion area percent and mass loss percent of steel bars in carbonated reinforced concrete
    图4 碳化水泥净浆的交流阻抗Nyquist曲线Fig.4 Nyquist plots of carbonated cement pastes
    图5 预埋钢筋的水泥净浆示意图及其电化学阻抗等效电路模型Fig.5 Schematic diagram of cement paste with embedded steel bar and its equivalent circuit model
    图6 碳化水泥净浆的极化曲线Fig.6 Polarization curves of carbonated cement pastes
    图7 碳化水泥净浆中钢筋的腐蚀速率Fig.7 Corrosion rate of steel bars in carbonated cement pastes
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引用本文

郭群,李晓珍,宋屹林,柳俊哲.钢筋阻锈剂在碳化钢筋混凝土中的阻锈作用[J].建筑材料学报,2023,26(1):21-28

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  • 收稿日期:2021-11-20
  • 最后修改日期:2021-12-24
  • 在线发布日期: 2023-02-01
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