含羟乙基纤维素醚对CSA水泥早期水化的影响
作者:
作者单位:

1.同济大学 先进土木工程材料教育部重点实验室,上海 201804;2.同济大学 材料科学与工程学院,上海 201804

作者简介:

王 茹(1975—),女,辽宁昌图人,同济大学教授,博士生导师,博士. E-mail: ruwang@tongji.edu.cn

通讯作者:

张震雷(1979—),女,河南济源人,同济大学高级工程师,博士. E-mail: zhangzhenlei@tongji.edu.cn

中图分类号:

TU528.01

基金项目:

国家自然科学基金资助项目(51872203, 51572196);中德科学中心资助项目(GZ 1290)


Effect of Cellulose Ethers with Hydroxyethyl Group on Early Hydration of CSA Cement
Author:
Affiliation:

1.Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804, China;2.School of Materials Science and Engineering, Tongji University, Shanghai 201804, China

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    研究了羟乙基纤维素(HEC)和高低取代度羟乙基甲基纤维素(H-HMEC、L-HEMC)对硫铝酸盐(CSA)水泥早期水化进程和水化产物的影响.结果表明:不同掺量L-HEMC均可促进CSA水泥在45.0 min~10.0 h内的水化;3种纤维素醚均先延缓CSA水泥溶解及其转化阶段的水化,后促进2.0~10.0 h内的水化;甲基的引入增强了含羟乙基纤维素醚对CSA水泥水化的促进作用,L-HEMC的促进作用最强;不同取代基和取代度的纤维素醚对水化前12.0 h内水化产物生成量的影响存在显著差异,HEMC对水化产物的促进作用强于HEC,L-HEMC改性CSA水泥浆体在水化2.0、4.0 h时生成钙钒石和铝胶的量最多.

    Abstract:

    The effects of hydroxyethyl cellulose(HEC) and hydroxyethyl methyl cellulose with high and low substitution degree (H-HEMC, L-HEMC) on the early hydration process and hydration products of calcium sulphoaluminate(CSA) cement were studied. The results show that different dosages of L-HEMC can promote the hydration of CSA cement from 45.0 min to 10.0 hours. All the three kinds of cellulose ethers firstly delay the hydration of CSA cement during the dissolution and transformation stage, and then promote the hydration of CSA cement from 2.0 hours to 10.0 hours. The introduction of methyl group enhances the hydration promotion effect of cellulose ether on CSA cement, and the promoting effect of L-HEMC is the strongest. There are significant differences in the effect of different substituent groups and substitution degree on the production of hydration products produced within 12.0 hours. The promotion effect of HEMC on hydration products is stronger than that of HEC. The amount of ettringite and aluminium hydroxide generated in L-HEMC modified cement paste are the most at hydration for 2.0 hours and 4.0 hours.

    参考文献
    相似文献
    引证文献
引用本文

王茹,刘科,万芹,李建,张震雷.含羟乙基纤维素醚对CSA水泥早期水化的影响[J].建筑材料学报,2022,25(8):836-842

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2021-07-04
  • 最后修改日期:2021-09-25
  • 录用日期:
  • 在线发布日期: 2023-09-15
  • 出版日期: