不同因素对建筑渣土泥浆流变性能的影响
作者:
作者单位:

1.同济大学 先进土木工程材料教育部重点实验室,上海 201804;2.同济大学 材料科学与工程学院,上海 201804

作者简介:

钟翼进(1998—),男,重庆开州人,同济大学硕士生.E-mail:1930615@tongji.edu.cn

通讯作者:

蒋正武(1974—),男,安徽潜山人,同济大学教授,博士生导师,博士.E-mail:jzhw@tongji.edu.cn

中图分类号:

TU521.3

基金项目:

国家自然科学基金资助项目(51878480, 52078369);宁波市科技创新2025重大专项项目(2019B10048);中央高校基本科研业务费专项资金资助项目


Influence of Different Factors on the Rheological Properties of Construction Waste Mud
Author:
Affiliation:

1.Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804, China;2.School of Materials Science and Engineering, Tongji University, Shanghai 201804, China

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    摘要:

    采用赫切尔-巴尔克模型拟合流变曲线,研究了含水率、外加剂(聚羧酸减水剂和季铵盐型表面活性剂)对建筑渣土泥浆在不同静置时间下流变性能的影响,并阐明了外加剂的作用机理.结果表明:随着含水率的增大,建筑渣土泥浆的流变性能参数均减小;随着2种外加剂掺量的增大,建筑渣土泥浆的初始表观黏度和塑性黏度先增大后减小;建筑渣土泥浆的屈服应力随着季铵盐型表面活性剂掺量的增加而一直增大,随着聚羧酸减水剂掺量的增大先增大后减小,相同掺量下聚羧酸减水剂的作用效果更好;外加剂分子间的排斥力与黏土对外加剂的吸附力两者之间的主导作用决定建筑渣土泥浆的流变性能.

    Abstract:

    The effect of water content, additives(polycarboxylic acid water reducer and quaternary ammonium surfactant) on the rheological properties of construction waste mud under different rest time were studied by fitting the rheological curve with Herschel-Bulkley model, and the action mechanism of additives was clarified. The results show that with the increase of water content, the rheological parameters of construction waste mud decrease. With the increase of the two additives content, the initial apparent viscosity and plastic viscosity of the construction waste mud first increase and then decrease. The yield stress of waste mud keeps increasing with increasing of the quaternary ammonium surfactant content, and first increase and then decrease with the increasing of the polycarboxylate superplasticizer content. The effect of polycarboxylate superplasticizer on the rheological properties of construction waste mud is better than that of quaternary ammonium surfactant under the same content. The dominant effect between the repulsive force of additive molecules and the adsorption force of the clay determines the rheological properties of construction waste mud.

    表 3 渣土泥浆的配合比及其静置时间Table 3 Mix proportions and rest time of waste mud
    表 2 外加剂的基本性能指标Table 2 Basic performance indexes of additives
    图1 渣土泥浆的粒径分布和XRD图Fig.1 Particle size distribution and XRD pattern of waste mud
    图2 动态剪切测试中剪切速率随时间的变化Fig.2 Change of shear rate with time in dynamic shear test
    图3 不同含水率渣土泥浆的表观黏度Fig.3 Apparent viscosity of waste mud with different water contents
    图4 不同含水率对渣土泥浆流变性能的影响Fig.4 Effects of different water contents on rheological properties of waste mud
    图5 不同含水率渣土泥浆的屈服应力和塑性黏度Fig.5 Yield stress and plastic viscosity of waste mud with different ww
    图6 不同聚羧酸减水剂掺量对WS50表观黏度的影响Fig.6 Effects of different contents of SP on apparent viscosity of WS50
    图7 不同聚羧酸减水剂掺量下的WS50流变性能Fig.7 Rheological properties of WS50 with different contents of SP
    图8 不同聚羧酸减水剂掺量下的WS50屈服应力和塑性黏度Fig.8 Yield stress and plastic viscosity of WS50 with different SP contents
    图9 不同季铵盐型表面活性剂掺量对渣土泥浆表观黏度和初始流变性能的影响Fig.9 Effect of different YZ contents on apparent viscosity and initial rheological properties of waste mud
    图10 不同外加剂掺量下的渣土泥浆屈服应力和塑性黏度Fig.10 Yield stress and plastic viscosity of waste mud with different additive contents
    图11 外加剂的分子结构示意图Fig.11 Molecular structure diagrams of additives
    图12 外加剂与黏土的层间吸附作用Fig.12 Interlayer absorption between additive and clay
    图13 不同掺量下外加剂对黏土的作用示意图Fig.13 Schematic diagrams of the effect of additives on clay under different contents
    表 1 渣土泥浆的化学组成Table 1 Chemical composition of waste mud
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钟翼进,何倍,任强,蒋正武.不同因素对建筑渣土泥浆流变性能的影响[J].建筑材料学报,2022,25(8):814-822

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  • 收稿日期:2021-06-16
  • 最后修改日期:2021-07-19
  • 在线发布日期: 2023-09-15
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