微波养护阶段碱激发粉煤灰胶凝材料的力学性能
作者:
作者单位:

1.西安建筑科技大学 材料科学与工程学院,陕西 西安 710055;2.西安建筑科技大学 教育部生态水泥工程研究中心,陕西 西安 710055;3.西安建筑科技大学 陕西省生态水泥混凝土工程技术研究中心,陕西 西安 710055

作者简介:

朱绘美(1986—),女,山东泰安人,西安建筑科技大学讲师,博士.E-mail: zhuhuimeitj@163.com

通讯作者:

李 辉(1971—),女,河南三门峡人,西安建筑科技大学教授,博士生导师,博士.主要研究方向:固体废弃物的资源化利用及新型水泥基材料的低碳制备.E-mail:sunshine_lihui@126.com

中图分类号:

TU526

基金项目:

国家自然科学基金资助项目(51828201);固废资源化利用与节能建材国家重点实验室开放资金资助项目(SWR-2021-009)


Mechanical Properties of Alkali-Activated Fly Ash Cementitious Materials under Microwave Curing Stages
Author:
Affiliation:

1.College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an 710055,China;2.Ministry of Education Ecological Cement Engineering Research Center, Xi'an University of Architecture and Technology, Xi'an 710055,China;3.Shaanxi Ecological Cement & Concrete Engineering Technology Research Center, Xi'an University of Architecture and Technology, Xi'an 710055,China

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    摘要:

    为探明微波养护与不同组分碱激发粉煤灰胶凝材料(AAFA)的适应性,采用掺加偏高岭土或硅灰来调整原材料硅铝比的方法,研究微波养护时不同硅铝比AAFA试件的力学性能发展规律,并分析AAFA的聚合反应产物和微观结构.结果表明:与传统蒸汽养护相比,微波养护后硅铝比大于1.92的AAFA试件早期强度发展更快,但微波养护时间过长会使试件呈现明显的强度倒缩;硅铝比小于1.97的AAFA试件内部可生成较多的富铝水化铝硅酸钠(N-A-S-H)凝胶相,具备更为致密的微结构和更优异的高温稳定性,使其在微波养护阶段的最大抗压强度较高,同时可避免强度倒缩现象出现.

    Abstract:

    In order to explore the adaptability of microwave curing to alkali-activated fly ash cementitious materials (AAFA), the mechanical properties of AAFA with different Si/Al ratios were studied by adding metakaolin or silica fume to adjust the Si/Al ratio. The hydration products and microstructure of AAFA were analyzed. The results show that compared with the traditional steam curing, the early strength development of AAFA with Si/Al ratio greater than 1.92 after microwave curing is faster, but the specimen with too long microwave curing time will show significant strength shrinkage. More alumina rich N-A-S-H gel phases can be generated inside the AAFA specimens with Si/Al ratio smaller than 1.97, which yield more compact microstructure and better high temperature stability, so that the maximum compressive strength is higher during the microwave curing stage, and the phenomenon of strength reduction can be avoided.

    表 2 AAFA试件的配合比Table 2 Mix proportion of AAFA specimens
    表 3 试件T-1.83、T-2.04、T-2.53采用微波养护至stage 4-Ⅰ、stage 4-Ⅱ的孔结构特征Table 3 Pore structure characteristics of specimen T-1.83, T-2.04 and T-2.53 under microwave curing to stage 4-Ⅰ and stage 4-Ⅱ
    图1 原材料的XRD图谱Fig.1 XRD patterns of raw materials
    图2 原材料的粒径分布Fig.2 Particle size distribution of raw materials
    图3 多级微波养护制度Fig.3 Multi-stage microwave curing regime
    图4 AAFA试件在不同微波养护阶段时的抗压强度Fig.4 Compressive strength of AAFA specimens under different microwave curing stages
    图5 粉煤灰和试件T-1.83、T-2.04、T-2.53微波养护至stage 4-Ⅰ的FTIR图谱Fig.5 FTIR spectra of fly ash and specimen T-1.83, T-2.04 and T-2.53 under microwave curing to stage 4-Ⅰ
    图6 T-1.83、T-2.04、T-2.53试件采用微波养护至stage 4-Ⅰ时的XRD图谱Fig.6 XRD patterns of specimen T-1.83, T-2.04 and T-2.53 under microwave curing to stage 4-Ⅰ
    图7 试件T-1.83采用微波养护至不同阶段的SEM照片Fig.7 SEM images of specimen T-1.83 under microwave curing to different stages
    图8 试件T-2.53采用微波养护至不同阶段的SEM照片Fig.8 SEM images of specimen T-2.53 under microwave curing to different stages
    表 1 粉煤灰和偏高岭土的化学组成Table 1 Chemical compositions of fly ash and metakaolin
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引用本文

朱绘美,张煜雯,迂晨,乔沛,李辉.微波养护阶段碱激发粉煤灰胶凝材料的力学性能[J].建筑材料学报,2022,25(6):558-564

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  • 收稿日期:2021-04-10
  • 最后修改日期:2021-06-22
  • 在线发布日期: 2022-08-01
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