石墨烯水泥基复合材料的电学性能
作者:
作者单位:

1.浙江科技学院 土木与建筑工程学院,浙江 杭州 310000;2.浙江工业大学 土木工程学院,浙江 杭州 310023

作者简介:

赵 昕(1989—), 女, 浙江诸暨人, 浙江科技学院讲师,博士. E-mail: xinzhao@zust.edu.cn

通讯作者:

刘金涛(1987—), 男, 河北保定人, 浙江工业大学副研究员,硕士生导师,博士. E-mail: jtliu@zujt.edu.cn

中图分类号:

TU528.58

基金项目:

国家自然科学基金资助项目(51908505);浙江省自然科学基金资助项目(LY21E080006)


Electrical Properties of Graphene Cement Based Composites
Author:
Affiliation:

1.School of Civil Engineering and Architecture, Zhejiang University of Science and Technology, Hangzhou 310000, China;2.College of Civil Engineering, Zhejiang University of Technology, Hangzhou 310023, China

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    摘要:

    为探究石墨烯水泥基复合材料的电学性能,通过四电极法测试了不同湿度、温度以及外荷载作用下复合材料的电阻率变化,考虑了石墨烯掺量对复合材料湿敏性、温敏性和压敏性的影响,并分析了其内在机理.结果表明:石墨烯水泥基复合材料的电阻率随着相对含水量的减少而逐渐增加,高掺量石墨烯可以降低复合材料的湿敏性;环境绝对温度的升高会导致石墨烯水泥基复合材料的电阻率呈现对数式下降,复合材料温敏性的临界石墨烯质量分数为0.8%;循环压缩荷载下,随着外荷载值的增加,石墨烯水泥基复合材料的电阻率下降,而外荷载值的降低会导致复合材料的电阻率上升;当石墨烯质量分数从0%增至0.8%时,复合材料的电阻变化率曲线离散性大幅降低、电阻变化率增大.

    Abstract:

    In order to investigate the electrical properties of graphene cement based composites, four-probe method was used to explore the influence of moisture, temperature and external cyclic loading on the electrical resistivity of cement based composites. Meanwhile, the effect of graphene content on moisture sensitive, thermal sensitive and pressure sensitive properties of composites was also studied . The results show that the electrical resistivity of graphene cement based composites increases with the increase of relative water content, and the reduction of resistivity sensitivity to water content was observed in high graphene content composites. The electrical resistivity of composites logarithmic decreases with the increase of absolute temperature, where 0.8% is the critical graphene content. Under external cyclic loading, the electrical resistivity of composites decreases with the increase of external load value, whereas it increases with the decrease of external load value. With the graphene content increase from 0% to 0.8%, the dispersion of resistance change rate curves reduced remarkably and the resistance change rate of composites increase.

    表 1 石墨烯薄片的性能参数Table 1 Performance parameters of graphene sheets
    表 2 石墨烯水泥净浆的配合比Table 2 Mix proportions of graphene cement paste
    表 3 各组试件拟合曲线的拟合参数Table 3 Parameters of fitted curves of each group
    图1 石墨烯的微观形貌图Fig.1 Micrograph of graphene
    图2 石墨烯粒径分布Fig.2 Particle size distribution of graphene
    图3 四电极法电阻率测试试件Fig.3 Sample for electrical resistance testing in four-probe method (size:mm)
    图4 不同含水率下水泥基复合材料的极化过程Fig.4 Polarization process of cement based composites with different water content
    图5 各组试件电阻率与相对含水量的关系Fig.5 Relationships between relative water content and resistivity of each group
    图6 环境绝对温度对石墨烯水泥基复合材料电阻率的影响Fig.6 Influence of environmental absolute temperature on the resistivity of graphene cement based composites
    图7 不同石墨烯掺量的水泥基复合材料压敏曲线Fig.7 Pressure sensitive curves of graphene cement based composites
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引用本文

赵昕,黄存旺,傅佳丽,刘金涛.石墨烯水泥基复合材料的电学性能[J].建筑材料学报,2022,25(1):8-15

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  • 收稿日期:2020-09-30
  • 最后修改日期:2020-10-21
  • 在线发布日期: 2022-01-19
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