碳化与氯盐复合作用下硫氧镁胶凝材料的护筋性
作者:
作者单位:

1.宁波大学 土木与环境工程学院,浙江 宁波 315211;2.青岛农业大学 建筑工程学院,山东 青岛 266109

作者简介:

巴明芳(1975—),女,山东滨州人,宁波大学教授,博士生导师,博士.E-mail: bamingfang@nbu.edu.cn

通讯作者:

柳俊哲(1964—),男,黑龙江哈尔滨人,青岛农业大学教授,博士生导师, 博士.E-mail: liujunzhe@nbu.edu.cn

中图分类号:

TU526

基金项目:

国家自然科学基金资助项目(51978346,51778302)


Corrosion Resistance of Steel Bars of Magnesium Oxy-sulfate Cementitious Material under the Combined Action of Carbonation and Chloride Salt
Author:
Affiliation:

1.School of Civil and Environmental Engineering, Ningbo University, Ningbo 315211, China;2.College of Architectural Engineering, Qingdao Agricultural University, Qingdao 266109, China

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    摘要:

    为探究硫氧镁(MOS)胶凝材料的护筋性,研究了自然养护、碳化、氯盐以及碳化和氯盐复合作用下MOS胶凝材料的电化学阻抗、钝化和脱钝钢筋的极化曲线以及锈蚀面积率.结果表明:碳化、氯盐单独作用下,MOS胶凝材料中钢筋的阻抗均低于自然养护下的相应阻抗,且随着龄期的延长,钝化钢筋的阻抗均呈现先减小后增大的趋势,脱钝钢筋的阻抗则持续减小;碳化和氯盐复合作用下MOS胶凝材料中钢筋的锈蚀程度明显增加,碳化和氯盐复合作用对MOS胶凝材料内部钢筋锈蚀程度具有叠加效应;各种腐蚀环境中脱钝钢筋的锈蚀程度均高于钝化钢筋.

    Abstract:

    In order to study the corrosion resistance of magnesium oxy-sulfate (MOS) cementitious materials, the electrochemical impedance, polarization curve and corrosion area ratio of passive and de-passive steel bars were investigated under natural curing, carbonation, chloride salt and combined action of carbonation and chloride salt. The results show that the impedance of steel bars under single carbonation and chloride salt condition is lower than that in natural curing. With the increased age, the impedance of passive steel bars decreases first and then increases, while that of de-passive steel bars decreases continuously. Under the combined action of carbonation and chloride salt, the electrochemical impedance of steel bars in MOS cementitious materials is further reduced, which reflects the superposition effect of combined action of carbonization and chloride on the corrosion degree of steel bars in MOS cementitious materials. The corrosion degree of de-passive steel bars is higher than that of passive steel bars under all curing conditions.

    表 1 MgSO4·7H2O的化学组成Table 1 Chemical compositions of MgSO4·7H2O
    表 3 MOS胶凝材料的配合比Table 3 Mix proportions of MOS cemented materials
    表 2 轻烧MgO粉的化学组成Table 2 Chemical compositions of light-burned MgO
    图1 轻烧MgO粉的XRD图谱和粒径分布图Fig.1 XRD spectrum and particle distribution of light-burned MgO
    图2 MOS胶凝材料的等效电路图Fig.2 Equivalent circuit diagram of MOScementitious material
    图3 氯盐作用下 MOS胶凝材料的电化学阻抗Fig.3 Electrochemical impedance of MOS cementitious materials under action of chloride salt
    图4 氯盐作用下MOS胶凝材料中钢筋的极化曲线(56 d)Fig.4 Polarization curves of steel bars in the MOS cementitious material under the action of chloride salt (56 d)
    图5 碳化作用下MOS胶凝材料的电化学阻抗Fig.5 Electrochemical impedance of MOS cementitious materials under carbonation
    图6 碳化作用下MOS胶凝材料中钢筋的极化曲线(28 d)Fig.6 Polarization curves of steel bars in MOS cementitious material under carbonation (28 d)
    图7 碳化和氯盐复合作用下 MOS胶凝材料的电化学阻抗Fig.7 Electrochemical impedance of MOS cementitious materials under carbonization and chloride salt
    图8 碳化和氯盐复合作用下MOS胶凝材料中钢筋极 化曲线(28 d)Fig.8 Polarization curves of steel bars in MOS cementitious materials under action of carbonization and chloride salt(28 d)
    表 4 MOS胶凝材料中钢筋的极化曲线参数Table 4 Parameters of polarization curve of steel bar in MOS cementitious material
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引用本文

巴明芳,张丹蕾,赵启俊,薛涛,柳俊哲.碳化与氯盐复合作用下硫氧镁胶凝材料的护筋性[J].建筑材料学报,2021,24(5):946-951

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  • 收稿日期:2020-06-11
  • 最后修改日期:2020-07-20
  • 录用日期:2020-08-07
  • 在线发布日期: 2021-12-15
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