快硬硫铝酸盐水泥在3D打印材料中的应用
作者:
作者单位:

1.郑州大学 土木工程学院,河南 郑州 450001;2.四川大学 深地科学与工程教育部重点实验室, 四川 成都 610065;3.河南省交通规划设计研究院股份有限公司,河南 郑州 450001

作者简介:

楚宇扬(2000—),男,河南鹿邑人,郑州大学本科生. E-mail:chuyuyang2000@163.com

通讯作者:

张 普(1982—),男,河南周口人,郑州大学副教授,博士生导师,博士.E-mail:zhpu@zzu.edu.cn

中图分类号:

TU528

基金项目:

国家自然科学基金资助项目(U1904177);交通部重点研发项目(2018-MS5-136);河南省交通运输科技计划项目(2018J2,2019J-2-10,2020J-2-7)


Application of Rapid Hardening Sulphoaluminate Cement in 3D Printing Material
Author:
Affiliation:

1.School of Civil Engineering, Zhengzhou University, Zhengzhou 450001, China;2.Key Laboratory of Deep Underground Science and Engineering, Ministry of Education, Sichuan University, Chengdu 610065, China;3.Henan Provincial Communications Planing & Design Institute Co., Ltd., Zhengzhou 450001, China

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    摘要:

    将快硬硫铝酸盐水泥(R·SAC)掺加到普通硅酸盐水泥(P·O)中得到混合水泥,以改善P·O 3D打印材料凝结时间长、早期强度低的缺点,系统研究了R·SAC掺量对其凝结时间、力学性能、流动性和堆积性的影响.结果表明:当R·SAC掺量为14%~20%时,促凝效果明显,有效降低了混合水泥净浆、砂浆的凝结时间,混合水泥净浆的初凝时间可以控制在40~70 min,满足3D打印的要求;掺加R·SAC可以提高材料的流动性,当R·SAC掺量为20%时,混合水泥砂浆的流动度比P·O砂浆提高了11 mm,稠度提高了15 mm;当混合水泥砂浆的流动度在160~175 mm时,可以满足3D打印材料的堆积性要求;掺加少量R·SAC对混合水泥砂浆的早期强度有一定的提升,但是其后期强度有所降低.

    Abstract:

    By adopting the method of mixing rapid hardening sulphoaluminate cement(R·SAC) with ordinary Portland cement(P·O) to improve the shortcomings of long setting time and low early strength of P·O 3D printing material, the effect of the R·SAC content on its setting time, mechanical property, fluidity and stacking performance was systematically studied. The results show that when the R·SAC content is 14%-20%, R·SAC has obvious effect of accelerating setting, and the setting time of cement paste and mortar has been effectively reduced, the initial setting time of the mixed cement paste can be controlled between 40-70 minutes, which meets the requirements of 3D printing. At the same time, the addition of R·SAC can improve the fluidity of the material. When the R·SAC content is 20%, the fluidity of the mixed cement mortar can be increased by 11 mm and the consistency by 15 mm compared to the P·O mortar. The fluidity of mixed cement mortar can meet the stacking performance requirements of 3D printing materials within 160-175 mm. The addition of a small amount of R·SAC has a certain improvement in the early strength of the mixed cement mortar, but its later strength has been reduced.

    表 1 P·O和R·SAC的物理力学性能Table 1 Physical and mechanical properties of P·O and R·SAC
    表 3 混合水泥净浆配比Table 3 Mix proportions of mixed cement pastes w/%
    图1 打印胶枪Fig.1 Print glue gun
    图2 水泥净浆的凝结时间Fig.2 Setting time of cement paste
    图3 水泥砂浆的凝结时间Fig.3 Setting time of cement mortar
    图4 R·SAC掺量对混合水泥砂浆力学性能的影响Fig.4 Effect of R·SAC content on mechanical property of mixed cement mortar
    图5 R·SAC掺量对混合水泥砂浆流动性的影响Fig.5 Effect of R·SAC content on fluidity of mixed cement mortar
    图6 减水剂掺量对混合水泥砂浆流动性的影响Fig.6 Effect of water reducing agent content on fluidity of mixed cement mortar
    图7 不同流动度下底层材料的相对变形量Fig.7 Relative deformation of bottom layer material under different fluidities
    图8 不同流动度下混合水泥砂浆的打印情况Fig.8 Printing situation of mixed cement mortar under different fluidities
    表 4 砂浆配合比Table 4 Mix proportions of mortars
    表 2 P·O和R·SAC的化学组成Table 2 Chemical compositions of P·O and R·SAC w/%
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引用本文

楚宇扬,徐金涛,刘烨,张普,汤意.快硬硫铝酸盐水泥在3D打印材料中的应用[J].建筑材料学报,2021,24(5):930-936

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  • 收稿日期:2020-05-31
  • 最后修改日期:2020-07-11
  • 录用日期:2020-07-14
  • 在线发布日期: 2021-12-15
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