SMC常温改性剂路用性能、机理及环保效益分析
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中央高校基本科研业务费专项资金资助项目(2682019ZT05);西南交通大学国际创新创业学院双创基金项目


Analysis of Road Performance, Mechanism and Environmental Benefits of SMC Normal Temperature Modifier
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    摘要:

    对SMC常温改性剂的挥发特性进行测定,并采用傅里叶红外光谱对SMC常温改性剂的改性机理进行初步解释;对不同SMC常温改性剂掺量(0%~12%)下的沥青混合料拌和温度、体积指标、稳定度、残留稳定度、冻融劈裂强度比、低温弯曲破坏应变等进行测试,并对沥青混合料在实验室拌和过程中产生的CO2、CO、SO2、NOx、PM25、PM10、苯并(a)芘进行了定量检测.结果表明:(1)SMC常温改性剂属于一种含酰胺键的表面活性剂,与沥青混合后,所形成的改性沥青具有较强挥发性,应在启用后的4h内完成生产和施工并保证100h的养护时间;(2)SMC常温改性剂可以在0%~8%的掺量范围内优化沥青混合料低温抗裂性能,但对其强度、高温车辙性能、水稳性能均存在劣化作用;(3)为保证沥青混合料路用质量要求,对于SMC13级配,适宜的SMC常温改性剂掺量为6%~10%,对于SMC20级配则为6%~8%,在此掺量范围内,对应的沥青混合料拌和温度可降至85~105℃,压实温度降至75~95℃,虽然离常温拌和与摊铺这一目标还有一定差距,但拌和过程中产生的CO2、CO、SO2、NOx、苯并(a)芘排放得到了有效抑制,减排均超过40%.

    Abstract:

    The volatile characteristics of SMC normal temperature modifier were determined, and the modification mechanism was preliminarily explained by Fourier transform infrared spectroscopy. Furthermore, with different SMC content(0%12%), the mixture mixing and compaction temperature, volume index, stability, residual stability, freeze thaw splitting strength ratio, low temperature bending failure strain were tested. Quantitative determination of CO2,CO,SO2,NOx,PM25,PM10 and benzo(a) pyrene(BaP) produced during the process of mixing in laboratory was carried out. The results show that:(1) the SMC normal temperature modifier belongs to the amide bond containing surfactant, and the modified asphalt formed after mixing asphalt with SMC has strong volatility. The production and construction should be completed within 4hours after the addition of SMC normal temperature modifier and 100hours maintenance time should be guaranteed.(2) SMC can optimize low temperature crack resistance in the range of 0%8% of SMC, but it has deterioration effect on strength, high temperature rutting performance and water stability.(3) To ensure the quality requirements for road use, for SMC 13gradation and SMC 20gradation, the suitable use level of SMC is 6%10% and 6%8% respectively. Under this use level the corresponding mixing temperature range can be reduced to 85105℃, and the compaction temperature range is reduced to 7595℃. Although there is still a certain gap from the normal temperature mixing and paving, the emission of CO2,CO,SO2,NOx and benzo(a)pyrene generated during the mixing process is effectively suppressed, and the emission reduction exceeds 40%.

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罗浩原,栗振坤,郑鹏飞,欧阳铖霏,邱延峻. SMC常温改性剂路用性能、机理及环保效益分析[J].建筑材料学报,2020,23(5):1144-1152

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  • 收稿日期:2019-04-28
  • 最后修改日期:2019-05-27
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  • 在线发布日期: 2020-11-06
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