高延性偏高岭土粉煤灰基地聚合物的制备及拉伸性能
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国家自然科学基金资助项目(51508329);桥隧工程系列超高性能混凝土技术研究项目(CTKY ZDXM 2018 003)


Preparation and Tensile Property of Metakaolin Fly Ash Based Engineered Geopolymer Composites
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    摘要:

    在水玻璃和氢氧化钠配制而成的碱激发剂作用下,以粉煤灰为主要原材料,偏高岭土为辅助材料,共同制备了高延性偏高岭土粉煤灰基地聚合物(MFAEGC),并研究了其单轴拉伸性能.结果表明:MFAEGC试件经单轴拉伸后具有良好的多缝开裂特性,裂缝分布均匀,裂缝间距为2~5mm,残余裂缝平均宽度约为25μm;最优配比试件3,7,28d抗拉强度分别为32,37,38MPa,极限拉伸应变可高达68%,64%,52%,初裂强度分别为14,15,19MPa;3种因素对MFAEGC试件抗拉性能的影响程度依次为养护温度>偏高岭土掺量>PVA纤维掺量.通过三点弯曲和单裂缝拉伸试验计算出的MFAEGC应变硬化性能(PSH)指数与由单轴拉伸试验得到的极限拉伸应变变化趋势相吻合,由此很好地解释了这一材料的高延性机理.

    Abstract:

    Activated by alkaline activator prepared by sodium metasilicate and sodium hydroxide, the metakaolin fly ash based engineered geopolymer composites(MFA EGC) was prepared using fly ash as the main raw material and metakaolin as auxiliary material, and uniaxial tensile property of MFA EGC were explored. The results show that MFA EGC has good multi cracking behavior after uniaxial direct tensile test. The distribution of cracks is uniform, and the crack spacing is in the range of 25mm, and the average width of residual cracks is about 25μm. The tensile strength for the optimum proportion at 3, 7, 28d is 32, 37, 38MPa respectively, and the ultimate tensile strain can be up to 68%, 64% and 52% respectively, and initial crack strength is 14, 15, 19MPa respectively. The order of influence of factors on the tensile properties is as follows:curing temperature>metakaolin content>PVA fiber content. Through the three point bending and the single crack tensile test, it is shown that the calculated pseudo strain hardening(PSH) index is consistent with the trend of ultimate tensile strain by the uniaxial direct tensile test, which can well explain its high ductility.

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阚黎黎,王文松,王家豪,段昕智.高延性偏高岭土粉煤灰基地聚合物的制备及拉伸性能[J].建筑材料学报,2019,22(5):673-680

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  • 收稿日期:2018-08-08
  • 最后修改日期:2018-09-26
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  • 在线发布日期: 2019-11-02
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