Through penetration, softening point, ductility, four components test and dynamic shear rheological(DSR) test, the high temperature rheological properties of polyphosphoric acid(PPA) modified asphalt binders were studied and compared with the matrix asphalt and SBS modified asphalt binder. The results show that the addition of PPA can improve asphalt high temperature rheological properties significantly. With the increase of PPA content, softening point improves, penetration decreases, complex shear modulus increases, phase angle decreases, and rutting factor increases for PPA modified asphalt binders, indicating that asphalt high temperature properties improve with the addition of PPA. DSR tests indicate that the high temperature properties of modified asphalt binder with 1.0%(by mass) PPA equals to that with 4.0% SBS . Almost every 0.5% increase of PPA content makes the high temperature PG level raise a level. The addition of PPA has obvious influence on the asphalt binder component, the content of asphalt is notably increased, the gum content is significantly reduced, and the high temperature resistance to permanent deformation of asphalt binder can be improved by using PPA.
[1]BAUMGARDNER G L,MASSON J F,HARDEE J R,et al.Polyphosphoric acid modified asphalt:Proposed mechanisms[C]∥Asphalt Paving Technology:Association of Asphalt Paving Technologists Proceedings of the Technical Sessions.Long Beach,CA,United States:Association of Asphalt Paving Technologist,2005,74:283 305.
[2]MIKNIS F P,PAULI A T,BEEMER A,et al.Use of NMR imaging to measure interfacial properties of asphalts[J].Fuel,2005,84(9):1041 1051.
[3]HO S,ZANZOTTO L,MACLEOD D.Impact of different types of modification on low temperature tensile strength and T critical of asphalt binders[J].Transportation Research Record,2002,1810:1 8.
[4]XIAO F P,AMIRKHANIAN S,WANG H N,et al.Rheological property investigations for polymer and polyphosphoric acid modified asphalt binders at high temperatures[J].Construction and Building Materials,2014,64:316 323.
[5]REINKE G A.Review of the current situation regarding polyphosphoric acid modified binders[C]∥The Association of Modified asphalt Producers Meeting.Saint Louis,USA:AMAP,2005,68:386 410.
[6]KODRAT I,SOHN D,HESP S M.Comparison of polyphosphoric acid modified asphalt inders with straight and polymer modified materials[J].Transportation Research Record,2007,1998:47 55.
[7]ZEGEYE E T,MOON K H,TUROS M,et al.Low temperature fracture properties of polyphosphoric acid modified asphalt mixtures[J].Journal of Materials in Civil Engineering,2012,24(8):1089 1096.
CAO Xiaojuan,ZHANG Zhenxing,HAO Peiwen,et al.Effect of polyphosphoric acid on the high and low temperature property of matrix asphalt mixture[J].Journal of Wuhan University of Technology,2014,36(6):47 53.(in Chinese)
ZHANG Henglong,SHI Caijun,YU Jianying,et al.Modification and its mechanism of different asphalts by polyphosphoric acid[J].Journal of Building Materials,2013,16(2):255 260.(in Chinese)
FU Liqiang,WANG Ziling,HUANG Xiaoming,et al.Performance research of polyphosphoric acid modified asphalt[J].Journal of Highway and Transportation Research and Development,2008,25(2):16 19,44.(in Chinese)