纳米改性混凝土界面过渡区的多尺度表征
作者:
基金项目:

国家自然科学基金资助项目(51378011)


Multi scale Characterization of Interfacial Transition Zone in Nano Modified Concrete
Author:
  • 摘要
  • | |
  • 访问统计
  • |
  • 参考文献 [18]
  • |
  • 相似文献
  • |
  • 引证文献
  • | |
  • 文章评论
    摘要:

    从多尺度综合研究了纳米SiO2对混凝土界面过渡区早期力学性能的影响.在宏观尺度上,主要测试了纳米改性混凝土的弹性模量及抗压、抗折强度,在微观尺度上,采用纳米压痕对其界面过渡区进行了压痕模量及其频数分布分析.结果表明:掺入纳米SiO2后,无论水泥石还是混凝土,其早期强度及弹性模量均有所提高,且混凝土强度的提高尤为明显;纳米改性混凝土界面区的孔隙和缺陷显著减少,且形成了更高密度的CSH凝胶相,使其压痕模量与水泥石的压痕模量接近.

    Abstract:

    The effect of nano SiO2 on the early mechanical properties of interfacial transition zone in concrete was studied at multi scale levels. At macrolevel, the static modulus of elasticity, compressive and flexural strength were measured; at microlevel, the values and distribution of indentation modulus in interfacial transition zone were analyzed by nano indentation. Results show that the addition of nano SiO2 improves the early strength and modulus of both cement paste and concrete, in particular, a much significant increase of strength for concrete was observed. The amount of micro pores and defects decreases remarkably and C S H gel with higher density forms in ITZ of concrete modified by nano SiO2, thus the indentation modulus of ITZ is much closer to that of bulk paste.

    参考文献
    [1]陈惠苏,孙伟,STROEVEN P.水泥基复合材料集料与浆体界面研究综述(二):界面微观结构的形成、劣化机理及其影响因素[J].硅酸盐学报,2004,32(1):70 79.
    CHEN Huisu,SUN Wei,STROEVEN P.Interfacial transition zone between aggregate and paste in cementitious composites(Ⅱ):Mechanism of formation and degradation of interfacial transition zone microstructure,and its influence factors[J].Journal of the Chinese Ceramic Society,2004,32(1):70 79.(in Chinese)
    [2]SCRIVENER K L,CRUMBIE A K,LAUGESEN P.The interfacial transition zone(ITZ) between cement paste and aggregate in concrete[J].Interface Science,2004,12(4):411 421.
    [3]马一平.提高水泥石集料界面粘结强度的研究[J].建筑材料学报,1999,2(1):29 32.
    MA Yiping.Research on improving the interfacial bond stren gth of cement paste aggregate[J].Journal of Building Materials,1999,2(1):29 32.(in Chinese)
    [4]王彩辉,蒋金洋,任春福,等.基于无机纳米混凝土的研究进展[J].材料导报,2011,25(17):41 44.
    WANG Caihui,JIANG Jinyang,REN Chunfu,et al.The study progress of inorganic nano concrete[J].Materials Review,2011,25(17):41 44.(in Chinese)
    [5]BERRA M,CARASSITI F,MANGIALARDI T,et al.Effects of nano silica addition on workability and compressive strength of Portland cement pastes[J].Construction and Building Materials,2012,35(10):666 675.
    [6]ZHANG Minhong,ISLAM J,PEETHAMPARAN S.Use of nano silica to increase early strength and reduce setting time of concretes with high volumes of slag[J].Cement and Concrete Composites,2012,34(5):650 662.
    [7]SAID A M,ZEIDAN M S,BASSUONI M T,et al.Properties of concrete incorporating nano silica[J].Construction and Building Materials,2012,36(12):838 844.
    [8]GAO Yun,de SCHUTTER G,YE Guang,et al.The ITZ microstructure,thickness and porosity in blended cementitious composite:Effects of curing age,water to binder ratio and aggregate content[J].Composites Part B:Engineering,2014,60(4):1 13.
    [9]何智海,钱春香,张异,等.等强混凝土界面过渡区的纳米压痕表征[J].建筑材料学报,2014,17(6):1082 1086.
    HE Zhihai,QIAN Chunxiang,ZHANG Yi,et al.Nanoindentation characteristics of interfacial transition zones in concrete under equal compressive strength[J].Journal of Building Materials,2014,17(6):1082 1086.(in Chinese)
    [10]MONDAL P,SHAH S P,MARK S L.A reliable technique to determine the local mechanical properties at the nanoscale for cementitious materials[J].Cement and Concrete Research,2007,37(10):1440 1444.
    [11]HU C,LI Z.A review on the mechanical properties of cement based materials measured by nanoindentation[J].Construction and Building Materials,2015,90(8):80 90.
    [12]ZHAO S,SUN W.Nano mechanical behavior of a green ultra high performance concrete[J].Construction and Building Materials,2014,63(7):150 160.
    [13]NILI M,EHSANI A.Investigating the effect of the cement paste and transition zone on strength development of concrete containing nanosilica and silica fume[J].Materials & Design,2015,75(6):174 183.
    [14]CHEN Huisu,ZHU Zhigang,LIU Lin,et al.Aggregate shape effect on the overestimation of ITZ thickness:Quantitative analysis of Platonic particles[J].Powder Technology,2016,289(2):1 17.
    相似文献
    引证文献
引用本文

徐晶,王彬彬,赵思晨.纳米改性混凝土界面过渡区的多尺度表征[J].建筑材料学报,2017,20(1):7-11

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2015-10-01
  • 最后修改日期:2016-05-12
  • 在线发布日期: 2017-03-07
文章二维码