淀粉基水泥水化热调控材料的制备及作用机理
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国家自然科学基金资助项目(51302114,51408270,51408274);江苏省自然科学基金资助项目(BK20131010,BK20131011);国家高技术研究发展计划(863计划)项目(2012AA021405)


Preparation and Action Mechanism of Starch Based Cement Hydration Heat Regulating Materials
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    摘要:

    通过热解并酶解玉米淀粉,制备了一种水泥水化热调控材料(HHRM),并使用X射线衍射(XRD)、扫描电镜(SEM)和凝胶渗透色谱(GPC)对其进行了表征.结果表明:HHRM为结晶度较高的多孔结构,当HHRM以固体粉末状态掺入时,可降低水泥水化放热速率峰值约55%,以溶解状态掺入时则仅仅延长了水泥水化诱导期.通过试验推测,HHRM是通过缓慢释放糖链到水泥颗粒上而起到了降低水泥水化放热速率峰值的作用.

    Abstract:

    A cement hydration heat regulating material(HHRM), which was prepared by pyrolysis and enzymatic hydrolysis of corn starch, was characterized by X ray diffraction(XRD), scanning electron microscopy(SEM) and gel permeation chromatography(GPC). Performance tests show that, the material has a porous structure with a higher degree of crystallization. When used in solid powder, it can reduce the cement hydration exothermic rate peak about 55%, however, when added in dissolved state, it only extended the induction period of hydration. It is proposed that reduction of the cement hydration exothermic rate peak is due to the HHRM slow releases polysaccharide chains to cement particles.

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吕志锋,于诚,佘维娜,吴井志,王涛,冉千平.淀粉基水泥水化热调控材料的制备及作用机理[J].建筑材料学报,2016,19(4):625-630

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  • 收稿日期:2015-08-19
  • 最后修改日期:2015-12-07
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  • 在线发布日期: 2016-09-07
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