In order to overcome the limitation that TiO2 photocatalytic technology is difficult to be applied in asphalt pavement, the pavement performance and degradation effect of a new material for automobile exhaust degradation on all kinds of pavements were studied by experiments. Results show that mechanical properties and durabilities of the researched material can satisfy code requirements; use of asphalt binder layer can achieve better impact resistance, tensile bond strength and lowtemperature crack resistance, while use of epoxy resin binder layer can achieve better hightemperature stability and water stability; by coating the prepared material, macrotexture depth of pavement surface may decrease, but comprehensive antiskid performance can be improved due to the friction of rubber powder, and the British pendulum number of concrete pavement slab can be increased by 11.5%, whose antiskid performance improvement is better than that of asphalt pavement slab; in 1h, the material can degrade 95%(by mass) NO2 whose initial gas concentration is 0.002%(by mass), and with a good water stability, it can still degrade 35% NO2 even after soaking for 7d.