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引用本文:吴晨洁,柯龙,王德志,张海伟,赵晏.全废水超硫酸盐水泥混凝土的力学与抗冻性能[J].建筑材料学报,2024,27(10):931-937
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全废水超硫酸盐水泥混凝土的力学与抗冻性能
吴晨洁1,柯龙1,王德志1,2,3,4,张海伟1,赵晏1
1.宁夏大学 土木与水利工程学院,宁夏 银川 750021;2.宁夏大学 宁夏节水灌溉与水资源调控工程技术研究中心,宁夏 银川 750021;3.宁夏大学 旱区现代农业水资源高效利用教育部工程研究中心,宁夏 银川 750021;4.宁夏大学 宁夏土木工程防震减灾工程技术研究中心,宁夏 银川 750021
摘要:
利用混凝土搅拌站废水作为拌和水,制备了超硫酸盐水泥混凝土,研究了其力学和抗冻性能,并通过扫描电镜、X射线衍射仪及低场核磁共振观察了混凝土的微观形貌、物相组成及孔隙特征.结果表明:全废水超硫酸盐水泥混凝土早期抗压强度较低,后期抗压强度发展较快;水胶比0.41的全废水超硫酸盐水泥混凝土掺入80%矿渣后,其28 d抗压强度可达48.6 MPa,矿渣中的玻璃体被废水中的OH-溶解,生成钙矾石和水化硅酸钙,从而使混凝土微观形貌致密,孔隙率低至2.5%,100次冻融后混凝土的孔隙率增加至3.5%,T2驰豫谱曲线明显向有害孔偏移,试件中出现裂缝与断层,强度和抗冻性能降低.
关键词:  全废水  超硫酸盐水泥混凝土  力学性能  抗冻性能  机理分析
DOI:10.3969/j.issn.1007-9629.2024.10.008
分类号:TU528.3
基金项目:宁夏市重点研发计划项目(2022BEE03001);宁夏市自然科学基金资助项目(2023AAC03040);国家自然科学基金资助项目(52368037,51968060);宁夏市青年拔尖人才支持计划项目(2022118);宁夏市一流学科建设计划项目(NXYLXK2021A03)
Mechanical Property and Frost Resistance of Full Wastewater Supersulfated Cement Concrete
WU Chenjie1, KE Long1, WANG Dezhi1,2,3,4, ZHANG Haiwei1, ZHAO Yan1
1.School of Civil and Hydraulic Engineering, Ningxia University, Yinchuan 750021, China;2.Engineering Technology Research Center of Water-Saving and Water Resource Regulation in Ningxia, Ningxia University, Yinchuan 750021, China;3.Engineering Research Center for Efficient Utilization of Modern Agricultural Water Resources in Arid Regions, Ministry of Education, Ningxia University, Yinchuan 750021, China;4.Engineering Technology Research Center of Earthquake Protection and Disaster Mitigation in Civil Engineering in Ningxia, Ningxia University, Yinchuan 750021, China
Abstract:
Supersulfated cement concrete was prepared using wastewater from a concrete mixing plant as mixing water, its mechanical property and frost resistance were studied. The microstructure, phase composition and pore characteristics of concrete were observed by scanning electron microscopy, X-ray diffraction and low field nuclear magnetic resonance. The results show that early compressive strength of full wastewater supersulfated cement concrete is low, but it develops rapidly in the later stage. The 28 d compressive strength of full wastewater supersulfated cement concrete with a water binder ratio of 0.41 mixed with 80% slag can reach 48.6 MPa. The glass in slag is dissolves by OH- in wastewater to form ettringite and hydrated calcium silicate, so that the concrete microstructure is dense and the porosity is as low as 2.5%. After 100 times of freezing-thawing, the porosity of concrete increases to 3.5%, and T2 relaxation spectrum curve obviously shifts to harmful pores. Cracks and faults appeare in the specimens, and the strength and frost resistance decrease.
Key words:  full wastewater  supersulfated cement concrete  mechanical property  frost resistance  mechanism analysis
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