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引用本文:葛楠,胡卓君,刘艳明,施韬,徐锦皓.碳纳米纤维改性水泥基材料的变形及抗裂性能[J].建筑材料学报,2022,25(10):1015-1020
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碳纳米纤维改性水泥基材料的变形及抗裂性能
葛楠1,胡卓君1,刘艳明1,施韬1,2,徐锦皓1
1.浙江工业大学 土木工程学院,浙江 杭州 310023;2.浙江工业大学 浙江省工程结构与 防灾减灾技术研究重点实验室,浙江 杭州 310023
摘要:
用超声波分散和表面修饰法将碳纳米纤维(CNFs)分散到水泥基材料中,制备了CNFs改性水泥基材料,研究了其变形及抗裂性能.结果表明:CNFs能抑制水泥净浆的自收缩和干燥收缩,且显著延缓水泥砂浆的开裂时间;当CNFs掺量为0.05%时,CNFs改性水泥砂浆的开裂时间较空白组延长了48.5%;CNFs在水泥基材料中产生的桥连和拔出效应,延缓了裂纹的扩展,从而减少了CNFs改性水泥砂浆的收缩变形,提高了材料的抗裂性能.
关键词:  水泥基材料  碳纳米纤维  自收缩  干燥收缩  抗裂性能
DOI:10.3969/j.issn.1007-9629.2022.10.003
分类号:TU528.01
基金项目:国家自然科学基金资助项目(52078460,51778582);硅酸盐建筑材料国家重点实验室(武汉理工大学)2020年度开放基金重点项目(SYSJJ2020-06)
Deformation Properties and Crack Resistance of Carbon Nanofiber Modified Cement-Based Materials
GE Nan1, HU Zhuojun1, LIU Yanming1, SHI Tao1,2, XU Jinhao1
1.College of Civil Engineering, Zhejiang University of Technology, Hangzhou 310023, China;2.Key Laboratory of Civil Engineering Structure & Disaster Prevention and Mitigation Technology of Zhejiang Province, Zhejiang University of Technology, Hangzhou 310023, China
Abstract:
Carbon nanofibers (CNFs) were dispersed in the cement-based materials by ultrasonic dispersion and surface modification to prepare the carbon nanofibers modified cement-based materials. The deformation properties and crack resistance of CNFs modified cement-based materials were studied. The results show that CNFs can inhibit the autogenous shrinkage and drying shrinkage of cement paste, and significantly delay the cracking time of cement mortar. When the mass content of CNFs is 0.05%, the cracking time of CNFs modified cement mortar is 48.5% longer than that of the control group. The bridging and pull-out effects of CNFs in cement-based materials delay crack growth, thus reduce the shrinkage deformation of CNFs modified cement mortar and improve the crack resistance of the materials.
Key words:  cement-based material  carbon nanofiber  autogenous shrinkage  drying shrinkage  crack resistance