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引用本文:董瑾,刘效彬.脲酶诱导碳酸钙沉淀技术改良传统三合土的性能[J].建筑材料学报,2022,25(8):853-859
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脲酶诱导碳酸钙沉淀技术改良传统三合土的性能
董瑾,刘效彬
江苏师范大学 历史文化与旅游学院,江苏 徐州 221116
摘要:
采用扫描电镜、X射线衍射等研究了脲酶诱导碳酸钙沉淀(EICP)技术对三合土性能的影响.结果表明:随着豆粉质量浓度的增大,脲酶活性呈近似线性增长,其最适宜的环境pH值为3~11,当环境pH值为12时,脲酶活性急剧下降;与三合土空白样相比,脲酶改性三合土14 d碳化深度提高了94%~112%,28 d抗压强度提高了68.0%~103.0%,耐候性提高了150%~200%,60 d表面硬度提高了15.0%~18.3%;三合土空白样产生的碳酸钙晶体松散,脲酶的掺入使三合土中出现了长条状晶体和团簇状晶体,且随着豆粉质量浓度的增大,团簇状晶体相对增多,长条状晶体相对减少,使三合土的各项性能逐渐提高.
关键词:  古建筑修复  三合土  脲酶诱导碳酸钙沉淀  改良  性能
DOI:10.3969/j.issn.1007-9629.2022.08.012
分类号:TU52
基金项目:国家自然科学基金资助项目(51608236)
Performance of Traditional Tabia Improved by Enzyme Induced Calcite Precipitation Technology
DONG Jin, LIU Xiaobin
School of History Culture and Tourism, Jiangsu Normal University, Xuzhou 221116, China
Abstract:
The effect of enzyme induced calcite precipitation (EICP) technology on the properties of tabia was studied by means of scanning electron microscope and X-ray diffractometry. The results show that urease activity increases approximately linearly with increasing of soybean powder mass concentration, and its optimum pH value is 3-11. When the pH value is 12, the activity drops sharply. Compared with the control sample of tabia, the carbonization speed of tabia modified with urease increases by 94%-112% in 14 days, the compressive strength increases by 68%-103% in 28 days, the weather resistance increases by 150%-200%, the surface hardness increases by 15.0%-18.3% in 60 days. The calcium carbonate crystals produced by the control sample of tabia are loose. After adding urease, long-strip crystals and cluster-like crystals appear in the tabia, and with the increase of soybean powder mass concentration, the cluster-like crystals increase relatively, and the long-strip crystals decrease relatively, the performance of tabia also gradually improves.
Key words:  ancient building restoration  tabia  enzyme induced calcite precipitation  improve  performance