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引用本文:朱艳梅,张翼,蒋正武.羟丙基甲基纤维素对3D打印砂浆性能的影响[J].建筑材料学报,2021,24(6):1123-1130
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羟丙基甲基纤维素对3D打印砂浆性能的影响
朱艳梅1,2,3,张翼1,2,蒋正武1,2
1.同济大学 先进土木工程材料教育部重点实验室,上海 201804;2.同济大学 材料科学与 工程学院,上海 201804;3.上海市建筑科学研究院有限公司,上海 200032
摘要:
通过研究不同掺量羟丙基甲基纤维素(HPMC)对3D打印砂浆可打印性能、流变性能及力学性能的影响规律,探讨了HPMC的适宜掺量,并结合微观形貌分析其影响机理.结果表明:砂浆流动度随着HPMC掺量增加而降低,即可挤出性随着HPMC掺量增加而降低,但流动性保持能力提高,加入适宜掺量的HPMC后砂浆仍具有良好的可挤出性;自重下形状保留率、贯入阻力均随HPMC掺量增加而显著增加,即随HPMC掺量增加,可堆叠性提高,可打印时间延长;从流变学的角度来看,随着HPMC掺量的增加,浆体表观黏度、屈服应力和塑性黏度显著增大,可堆叠性提升;触变性随HPMC掺量增加而先增大后减小,可打印性能提升;HPMC掺量过高会引起砂浆孔隙率增大、强度下降,建议HPMC掺量不超过0.20%.
关键词:  羟丙基甲基纤维素  3D打印  砂浆  可打印性能  流变性能
DOI:10.3969/j.issn.1007-9629.2021.06.001
分类号:TU528.59
基金项目:国家自然科学基金资助项目(51678442,51878480,51878481);中央高校基本科研业务费专项资金资助项目
Effect of Hydroxypropyl Methylcellulose Ether on Properties of 3D Printing Mortar
ZHU Yanmei1,2,3, ZHANG Yi1,2, JIANG Zhengwu1,2
1.Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804, China;2.School of Materials Science and Engineering, Tongji University, Shanghai 201804, China;3.Shanghai Research Institute of Building Science Co., Ltd., Shanghai 200032, China
Abstract:
The effects of different contents of hydroxypropyl methylcellulose ether(HPMC) on printability, rheology and mechanical properties of 3D printing mortar were studied. The suitable content of HPMC was determined, and its influence mechanism was analyzed by micro-morphology. The results reveal that the fluidity of mortar decreases with increasing HPMC content, so the extrudability decreases with HPMC content. But the fluidity retention ability increases, the mortar with HPMC still has good extrudability. The shape retention rate under self-weight and penetration resistance increase significantly with HPMC content, so the buildability and the printable time increase with increasing HPMC content. From the perspective of rheology, with the increase of HPMC content, the apparent viscosity, yield stress and plastic viscosity of the paste increase significantly, thus the buildability increases. The thixotropy increases at first and then decreases with increasing HPMC content, so the printability increases. However, higher HPMC content will lead to the increase of mortar porosity and the decrease of mortar strength. So it is recommended that the content of HPMC should not exceed 0.20%.
Key words:  hydroxypropyl methylcellulose ester(HPMC)  3D printing  mortar  printability  rheology
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