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引用本文:钟世云,李晋梅,韩冬冬,倪坤.聚合物乳液在水泥颗粒表面吸附的影响因素——乳液类型及聚灰比[J].建筑材料学报,2013,(5):739-743
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聚合物乳液在水泥颗粒表面吸附的影响因素——乳液类型及聚灰比
钟世云, 李晋梅, 韩冬冬, 倪坤
同济大学先进土木工程材料教育部重点实验室,上海201804
摘要:
为了研究影响聚合物颗粒在水泥表面吸附行为的因素,测试了掺乳液前后新拌浆体zeta电位随时间的变化,并研究了乳液类型及聚灰比(mL/mC)对水泥粒子吸附乳液中聚合物颗粒(简称乳液颗粒)的影响.结果表明:水泥粒子会吸附乳液颗粒,阴离子型乳液颗粒较非离子型乳液颗粒更易被水泥粒子吸附;随聚灰比的增加,水泥粒子对乳液颗粒的吸附量有一个最大值,且乳液颗粒在水泥表面的吸附是单层的.
关键词:  聚合物改性水泥浆  zeta电位  吸附  乳液类型  聚灰比
DOI:10.3969/j.issn.1007 9629.2013.05.001
分类号:
基金项目:
Factors Influencing the Adsorption Behavior of Latex Polymer onCement: Latex Type and Polymer/Cement Ratio
ZHONG Shi yun, LI Jin mei, HAN Dong dong, NI Kun
Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University,Shanghai 201804, China
Abstract:
In order to investigate the factors influencing the adsorption behavior of polymer particles on cement grains, the zeta potentials of fresh plain cement paste(PCP) and latex modified cement pastes(LMCP) were measured and the influences of latex type and the latex to cement ratio (mL/mC) on the adsorption behavior of polymer particles in the latex (for short as latex particles) on the cement grain were investigated. The results show that cement grains can adsorb latex particles, moreover, anionic latex particles are more easily adsorbed by cement grains than nonionic ones. With the increase of mL/mC the adsorbed latex particles on the cement grains increase to a constant level, therefore it can be concluded that the adsorption is single layered.
Key words:  polymer modified cement paste  zeta potential  adsorption  latex type  latex to cement ratio
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