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引用本文:魏国锋,方世强,李祖光,张秉坚.桐油灰浆材料的物理性能与显微结构[J].建筑材料学报,2013,(3):469-474
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桐油灰浆材料的物理性能与显微结构
魏国锋1, 方世强2, 李祖光2, 张秉坚3
1.安徽大学历史系,安徽合肥230039;2.浙江工业大学化学工程与材料学院,浙江杭州310014;3.浙江大学文物与博物馆学系,浙江杭州310027
摘要:
采用扫描电镜、X射线衍射、傅里叶变换红外光谱等技术手段,初步探讨了桐油灰浆的材料配方和理化性能,为其在古代建筑、船舶等文化遗产保护中的应用提供理论依据.结果显示,用Ca(OH)2和熟桐油制备的桐油灰浆综合性能最佳,其90d抗压强度和剪切强度较普通石灰浆分别提高了72%和245%,吸水系数仅为普通石灰浆的1/620,抗氯离子侵蚀能力和耐冻融循环等性能均大大改善;该桐油灰浆的优良性能源于桐油的强固化能力以及桐油与Ca(OH)2反应形成的致密结构.
关键词:  桐油  灰浆  传统材料  复合材料  文物保护
DOI:10.3969/j.issn.1007 9629.2013.03.016
分类号:
基金项目:
Physical Properties and Microscopic Structure of Tung Oil Lime Putty
WEI Guo feng1, FANG Shi qiang2, LI Zu guang2, ZHANG Bing jian3
1.Department of History, Anhui University, Hefei 230039, China;2.College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, China;3.Department of Cultural Heritage and Museology, Zhejiang University, Hangzhou 310027, China
Abstract:
The recipes and properties of tung oil lime putty were investigated by means of scanning electron microscope(SEM), X ray diffractometry(XRD) and Fourier transform infrared spectrometry (FTIR). The results show that the putty prepared with tung oil and Ca(OH)2 has the best properties. Compared with the common lime mortar, the 90 days compressive strength and shear strength of the tung oil Ca(OH)2 putty increase by 72% and 245% respectively and the water absorption coefficient reduces to 1/620 of that of the common lime mortar. The excellent performance of the tung oil Ca(OH)2 putty can be explained by the strong ability to cure of tung oil and the dense microstructure of the tung oil Ca(OH)2 putty.
Key words:  tung oil  mortar  traditional material  composite material  conservation of cultural relics