|
| 摘要: |
| 通过化学分析和差热分析试验手段,分别测定了试样中f-CaO的含量(质量分数,下同)和试样在烧成过程中的热变化曲线,并以试样中f-CaO的含量作为反应进度的量度,研究了MgO对高C3S水泥熟料矿物———C2S的影响.化学分析和差热分析试验结果显示,MgO的加入降低了试样中f-CaO的含量,降低了CaCO3的分解峰温和C2S矿物形成的初始温度.热力学函数计算分析显示,MgO的加入增大了n(CaO)/n(SiO2)比值,从而增大了矿物形成的反应自由能数值. |
| 关键词: 化学分析,差热分析,热力学 |
| DOI： |
| 分类号:TU528.0 |
| 基金项目:国家重点基础研究发展规划(973)资助项目(2001CB610704) |
|
| Influence of MgO on Formation of C2S |
|
LI Hao-xin WANG Pei-ming XIONG Shao-bo
|
| Abstract: |
| By testing the content of free-CaO in the sample,the content of free-CaO in the sample was regarded as the measurement of reacting.The influence of MgO on the formation of mineral of C_2S which is the component of highC_3S cement was studied by the research methods of chemical analysis and thermal analysis.It is found that appropriate adding of MgO helps absorption of free-CaO,and benefited the formation of mineral of C_2S;furthermore,lowers decomposition temperature of CaCO_3.At last,regarding the thermodynamic reason of this phenomenon,it is found that adding MgO increases the ratio of n(CaO)/n(SiO_2),enhances the thermodynamic function of C_2S mineral formation. |
| Key words: chemical analysis,differential thermal analysis,thermodynamics |
