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引用本文:王国建.有机硅氧烷/丙烯酸酯乳液的无皂共聚合研究[J].建筑材料学报,2002,(3):269-273
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有机硅氧烷/丙烯酸酯乳液的无皂共聚合研究
王国建
作者单位
摘要:
采用表面活性单体烯丙基-2-羟丙基醚磺酸钠(NaAPS)和丙烯酸聚羟基丙酸酯(PHPA)作为乳化体系进行无皂硅氧烷/丙烯酸酯(硅丙)共聚乳液的制备,研究了表面活性单体种类,共用和用量对硅丙共聚乳液及其涂料性能的影响。结果表明,与普通硅丙共聚乳液相比,无皂硅丙共聚乳液涂料的涂膜有较好的综合性能。
关键词:  无皂乳液聚合 有机硅 聚合物 丙烯酸酯乳液
DOI:
分类号:TQ316.334
基金项目:
Preparation of Siloxane/Acrylate Copolymeric Emulsion by a Soap-free Emulsion Polymerization
WANG Guo-jian
Abstract:
The soap-free siloxane/acrylate copolymeric emulsion was prepared by using sodium allyl-2-hydroxy propyl ether sulfonate(NaAPS) and poly(hydroxy propionic acid) acrylate(PHPA) as emulsifying system. The influence of types, cooperation and contents of surface-active monomers on the properties of soap-free siloxane/acrylate copolymeric emulsion and its coating were studied. The results show that the coating of the soap-free siloxane/acrylate copolymeric emulsion has better comprehensive properties than that of the general siloxane/acrylate emulsion.
Key words:  soap-free emulsion polymerization,polysiloxane,polyacrylate emulsion