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引用本文:张广成,杨青芳,李剑,兰立文.铝塑复合管专用热熔胶的研制[J].建筑材料学报,2000,(3):246-251
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铝塑复合管专用热熔胶的研制
张广成,杨青芳,李剑,兰立文
作者单位
摘要:
以过氧化二异丙苯为引发剂,以马来酸酐为单体,在单螺杆挤出机上进行了聚乙烯熔融接枝,用正交试验确定了引发剂、单体、阻交联剂对熔融指数的影响次序和合适的用量,用红外光谱和测试接枝率的方法证明了马来酸酐确已接枝到聚乙烯的大分子键上,不同密度聚乙烯接枝马来酸酐后,其与铝箔的粘接性研究表明:LLDPE-g-MAH具有最高的剥离强度,且当它与增流树脂共混后,即可作为铝塑复合管专用热熔胶。
关键词:  铝塑复合管 聚乙烯 热熔胶
DOI:
分类号:TQ325.04 O63
基金项目:
Development of Hot Melt Adhesive Used in Aluminum-plastics Compound Pipe
ZHANG Guang-cheng  YANG Qing-fang  LI Jian  LAN Li-wen
Abstract:
By using dicumyl peroxide as the initiator and maleic anhydride as the monor, polyethylene was melt to graft maleic anhydride in single screw extruder. The influence order of melt index and adaptable quantity for initiator, monor and crosslinking inhibitor was decided. It was testified by infrared spectrum and graft ratio measurement that maleic anhydride has been grafted to polyethylene large molecular chain. By studying the adhesiveness of aluminum with different density polyethylene grafted maleic anhydride, we conclude that LLDPE g MAH has the higest peel strength. LLDPE g MAH blending with the flow promotor resin can be used as the hot melt adhesive in aluminum plastics compound pipe.
Key words:  aluminum plastics compound pipe,polyethylene,maleic anhydride,graft,hot melt adhesive