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引用本文:吴知方,钱达兴,吴兆悦,黄文曰山,周蓓明.RO Al_2O_3 P_2O_5玻璃在模拟生理液中的侵蚀规律[J].建筑材料学报,1999,(3):
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RO Al_2O_3 P_2O_5玻璃在模拟生理液中的侵蚀规律
吴知方,钱达兴,吴兆悦,黄文曰山,周蓓明
作者单位
摘要:
对RO Al2O3 P2O5 系统玻璃中某些组分进行了去离子水及模拟生理液的耐蚀性测定.实验表明,RO Al2O3 P2O5 在模拟生理液中的侵蚀规律异于通常的Na2O CaO SiO2 P2O5 生物玻璃.试样的红外光谱验证了在该玻璃中兼有PO3 和P2O7 基团,具有稳定的Al(PO3)结构单元.
关键词:  磷酸盐玻璃,模拟生理液,侵蚀机理
DOI:
分类号:TQ171.113
基金项目:国家自然科学基金,863 高科技计划资助
Corrosion Mechanism of RO Al 2O 3 P 2O 5 Glass in Simulated Physiologic Solution
WU Zhi fang  QIAN Da xing  WU Zhao yue  HUANG Wen hai ZHOU Beiming
Abstract:
Chemical durability of selected compositions in RO Al 2O 3 P 2O 5(RAP) glass system(R=Zn,Mg) in deionic water and simulated physiologic solution were measured respectively. The measurements showed that the corrosion mechanism of RAP glass is quite different from that of Na 2O CaO SiO 2 P 2O 5 bioglass.The results from infrared spectrum experiments have confirmed the existence of PO 3 and P 2O 7 groups,as well as the stable Al(PO 3) group in the structure of RAP glass.
Key words:  phosphate glass,simulated physiological solution,corrosion mechanism